51670-51-0

Upstream product

• 524-42-5 1,2-naphthoquinone 
• 71-43-2 benzene 
• 2348-77-8 2-phenyl[1,4]naphthoquinone 
• 30069-66-0 phenyl-acetic acid-(3-phenyl-[1]naphthyl ester) 
• 5123-13-7 5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane 
• 98-80-6 phenylboronic acid 
• 103-80-0 phenylacetyl chloride 
• 859997-94-7 2-bromo-3-phenyl-1,4-naphthoquinone 
• 108-86-1 bromobenzene 
• 83-33-0 inden-1-one 
• 93433-54-6 2-benzylindan-1-ol 
• 16274-93-4 2-benzyl-1H-indene 
• 16307-30-5 2-benzyl-1-indanone 
• 831171-86-9 2-(2-oxo-3-phenylpropyl)benzaldehyde 

Downstream Products

• 51670-52-1 6-phenyl-benzo[a]phenazine 
• 108732-57-6 4-anilino-3-phenyl-1,2-naphthoquinone 
• 1150-59-0 2-hydroxy-3-phenyl-1,4-naphthoquinone 
• 108732-58-7 3-phenyl-4-p-tolythio-1,2-naphthoquinone 

Relevant academic research and scientific papers

Method for synthesizing 1,2-naphthoquinone and derivatives thereof

The present invention provides a method of synthesizing 1,2-naphthoquinone and derivatives thereof. The synthesis method takes an o-alkynyl chalcone compound represented by a formula (I) as an initialsubstance, ferric chloride or ferric nitrate as a catal

The 3-substitution of naphthalene-1,2-diones with boronic acids: A C-H functionalization approach to novel spirooxazine photochromics

The addition of alkyl and aryl boronic acids to naphthalene-1,2-diones in the presence of an excess of ammonium persulfate and catalytic silver nitrate to yield 3-functionalized naphthalene-1,2-diones is reported. The products of these reactions were then

Studies on the chemistry of 2-(2-oxo-3-phenylpropyl)-benzaldehydes: Novel total synthesis of 3-phenylnaphthalen-2-ols and 2-hydroxy-3-phenyl-1,4- naphthoquinones

We describe the first studies on the chemistry of 2-(2-oxo-3-phenylpropyl) benzaldehydes, which were converted into 3-benzylisochromen-1-ones via the corresponding 2-(2-oxo-3-phenylpropyl)benzoic acid. The 2-(2-oxo-3-phenylpropyl) benzaldehydes proved to be convenient starting materials for the synthesis of 3-phenyl-2-naphthols. Oxidation of the latter compounds resulted in a novel, efficient synthesis of 3-phenyl-1,2-naphthoquinones, which were efficiently transformed into 2-hydroxy-3-phenyl-1,4-naphthoquinones.

A New Synthesis of ortho-Quinones by Transition-Metal-Mediated Oxygenation of Phenols with tert-Butylhydroperoxide and the Mimoun Oxodiperoxo Molybdenum Complex * Py * HMPT

A specific oxygenation of phenols to ortho-quinones can be effected by a combination of the transition metal complexes Ti(OiPr)4, VO(acac)2, Zr(acac)4, Zr(OnPr)4 and tert-butylhydroperoxide (TBHP) or * Py * HMPT.Naphthols, anthracenols, phenanthrols and donor substituted mononuclear phenols are readily converted into the corresponding 1,2-quinones.Unhindered ortho-naphthoquinones can yield binaphthyls with unreacted starting material by Michael addition. - Key Words: ortho-Quinones / tert-Butyl hydroperoxide / Phenols, oxygenation

Quinones. Part 11. The Reaction of o-Aminothiophenol with o-Benzo- and o-Naphtho-quinones: A New Route to 1H-Phenothiazin-1-ones

1H-Phenothiazin-1-ones can be obtained by the condensation of o-aminothiophenol with 3,5-di-t-butyl- and 3-t-butyl-5-phenyl-o-benzoquinones.In the absence of large blocking groups the phenothiazinones are unstable.A methyl group at C-4 leads via the quinone-methide tautomer, to formation of a spiro-dimer the crystal structure of which was determined by X-ray analysis.By further reaction with o-aminothiophenol, 1H-phenothiazin-1-ones yield triphenodithiazines (benzothiazinophenothiazines). o-Naphthoquinones do not form benzo-1H-phenothiazin-1-ones with o-aminothiophenol.The parent compound yields 4-hydroxy-3H-benzophenothiazin-3-one by initial thiol addition at C-4 followed by rearrangement.