51757-79-0Relevant academic research and scientific papers
N,N-DICHLOROARENESULFONAMIDES IN THE IMINATION OF 2,2-DICHLOROVINYL SULFIDES
Drozdova, T. I.,Mirskova, A. N.,Levkovskaya, G. G.,Kalikhman, I. D.,Vitkovskii, V. Yu.,Voronkov, M. G.
, p. 1322 - 1326 (2007/10/02)
N,N-Dichlorobenzenesulfonamide acts as an iminating agent in reaction with 2,2-dichlorovinyl alkyl (phenyl) sulfides.The reaction leads to the formation of N-phenylsulfonyl-S-alkyl(phenyl)-S-(2,2-dichlorovinyl)sulfimides; the chlorination of 2,2-dichlorovinyl sulfides and reduction of N,N-dichlorobenzenesulfonamide take place as side reactions.
FREE-RADICAL CHLOROVINYLATION OF AROMATIC AND ALIPHATIC THIOLS
Mirskova, A. N.,Martynov, A. V.,Voronkov, M. G.
, p. 1766 - 1773 (2007/10/02)
During the free-radical thiylation of trichloroethylene with organic thiols β,β-dichlorovinyl sulfides are formed in a single stage.The reaction of alkanethiols with tetrachloroethylene under analogous conditions leads to trichlorovinyl sulfides.Oxidation of β,β-dichlorovinyl sulfides with hydrogen peroxide in acetic acid leads to the corresponding β,β-dichlorovinyl sulfones.
