51842-30-9

Basic information

• Product Name: methyl 4,6-di-O-acetyl-2,3-di-O-benzyl-α-D-glucopyranoside
• Synonyms: methyl 4,6-di-O-acetyl-2,3-di-O-benzyl-α-D-glucopyranoside
• CAS NO: 51842-30-9
• Molecular Weight: 458.508
• Mol File: 51842-30-9.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: methyl 4,6-di-O-acetyl-2,3-di-O-benzyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4,6-di-O-acetyl-2,3-di-O-benzyl-α-D-glucopyranoside(51842-30-9)
• EPA Substance Registry System: methyl 4,6-di-O-acetyl-2,3-di-O-benzyl-α-D-glucopyranoside(51842-30-9)

Safety Data

• Hazardous Substances Data: 51842-30-9(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 17791-36-5 methyl 2,3-di-O-benzyl-α-D-glucopyranoside 
• 29388-46-3 methyl 2,3-di-O-benzyl-α-D-galactopyranoside 
• 141-78-6 ethyl acetate 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 1454799-52-0 O-ethyl-S-[(((methyl 2,3,4-tri-O-benzyl-α-D-glucopyranos-6-yl)dimethylsilyl)methyl)]dithiocarbonate 
• 7177-79-9 methyl 2,3-di-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 7177-79-9 methyl 2,3-O-dibenzyl-4,6-O-benzylidene-α-D-glucopyranoside 

Downstream Products

• 18933-72-7 1,4,6-Tri-O-acetyl-2,3-di-O-benzyl-α-D-glucopyranose 
• 122596-67-2 1,4,6-Tri-O-acetyl-2,3-di-O-benzyl-β-D-glucopyranose 
• 142057-43-0 4,6-di-O-acetyl-2,3-di-O-benzyl-D-glucopyranose 
• 17791-36-5 methyl 2,3-di-O-benzyl-α-D-glucopyranoside 

Relevant articles and documents

Monoacetylation of carbohydrate diols via transesterification with ethyl acetate

Monoacetylation of secondary diols in protected monosaccharides was achieved with ethyl acetate as acyl donor and sodium tert-butoxide as a base. The regioseletivity of the reaction varied depending on the substrate. This new method provides a simple, fast, and efficient method to access selectively acetylated carbohydrates that is compatible with acid-sensitive protecting groups. CSIRO 2014.

Mild and efficient method for the cleavage of benzylidene acetals using HClO4-SiO2 and direct conversion of acetals to acetates

HClO4-SiO2 has been used successfully for the deprotection of benzylidene acetals and the direct conversion of benzylidene acetals to the corresponding di-O-acetates. The reactions are very fast and yields are excellent.

An easy approach for the acetylation of saccharidic alcohols. Applicability for regioselective protections

Cheap 4 ? molecular sieves can promote acetylation of carbohydrate hydroxyl functions with Ac2O in absence of any co-reagent. The procedure is compatible with the presence of a variety of acid labile protecting groups and can be exploited for regioselective protections.