51855-95-9Relevant academic research and scientific papers
Electronically Unsaturated Three-Coordinate Aluminum Hydride and Organoaluminum Cations
Prashanth, Billa,Bhandari, Mamta,Ravi, Satyam,Shamasundar,Singh, Sanjay
, p. 4794 - 4799 (2018)
New three-coordinate and electronically unsaturated aluminum hydride [LAlH]+[HB(C6F5)3]? (LH=[{(2,6-iPr2C6H3N)P(Ph2)}2N]H) and aluminum methyl [L
Imido-hydrido complexes of Mo(IV): Catalysis and mechanistic aspects of hydroboration reactions
Khalimon, Andrey Y.,Farha, Philip M.,Nikonov, Georgii I.
supporting information, p. 18945 - 18956 (2015/11/11)
Imido-hydrido complexes (ArN)Mo(H)(Cl)(PMe3)3 (1) and (ArN)Mo(H)2(PMe3)3 (2) (Ar = 2,6-diisopropylphenyl) catalyse a variety of hydroboration reactions, including the rare examples of addition of HBCat to nitriles to form bis(borylated) amines RCH2N(BCat)2. Stoichiometric reactivity of complexes 1 and 2 with nitriles and HBCat suggest that catalytic reactions proceed via a series of agostic borylamido and borylamino complexes. For complex 1, catalysis starts with addition of nitriles across the Mo-H bond to give (ArN)Mo(Cl)(NCHR)(PMe3)2; whereas for complex 2 stoichiometric reactions suggest initial addition of HBCat to form the agostic complex Mo(H)2(PMe3)3(η3-NAr-HBcat) (16).
