2467-16-5

Usage

Uses

Used in Polymers and Resins:
Tricyclohexyl borate is used as a flame retardant and plasticizer for enhancing the fire resistance and flexibility of polymers and resins. Its addition improves the safety and performance of these materials in various applications.
Used in Coatings:
In the coatings industry, tricyclohexyl borate is utilized as a flame retardant to increase the fire resistance of coatings applied to different surfaces, providing additional protection against fire hazards.
Used in Electrical Insulation Materials:
Tricyclohexyl borate is employed as a key component in the production of electrical insulation materials, ensuring the safety and reliability of electrical systems by reducing the risk of fire.
Used in Construction Materials:
In the construction industry, tricyclohexyl borate is used to improve the fire resistance of various building materials, contributing to the overall safety and durability of structures.
Used in Automotive Parts:
Tricyclohexyl borate is utilized in the manufacturing of automotive parts to enhance their fire resistance and flexibility, ensuring the safety and performance of vehicles.
Despite the effectiveness of tricyclohexyl borate as a flame retardant, there are concerns regarding its potential environmental and health impacts. This has led to ongoing research and regulation of its use in certain applications to ensure the safety and sustainability of products containing this chemical compound.

InChI:InChI=1/C18H33BO3/c1-4-10-16(11-5-1)20-19(21-17-12-6-2-7-13-17)22-18-14-8-3-9-15-18/h16-18H,1-15H2

Upstream product

• 688-71-1 tri-n-propyl borate 
• 108-93-0 cyclohexanol 
• 4887-24-5 triacetoxyborane 
• 108-94-1 cyclohexanone 
• 11113-50-1 boric acid 

Downstream Products

• 108-94-1 cyclohexanone 
• 110-83-8 cyclohexene 
• 108-93-0 cyclohexanol 
• 827-52-1 1-phenyl-1-cyclohexane 
• 51855-95-9 2-cyclohexyloxy-benzo[1,3,2]dioxaborole 
• 55089-04-8 Ethylen-cyclohexyl-borat 
• 1172-69-6 tris(cyclohexyloxy)boroxine 
• 108678-42-8 Cyclohexyloxy-diethyl-borane 
• 42927-42-4 dicyclohexyl sulfate 
• 4351-54-6 cyclohexyl formate 

Relevant academic research and scientific papers

Sodium Aminodiboranate, a New Reagent for Chemoselective Reduction of Aldehydes and Ketones to Alcohols

Sodium aminodiboranate (NaNH 2(BH 3) 2, NaADBH) is a new member of the old borane family, which exhibits superior performance in chemoselective reduction. Experimental results show that NaADBH can rapidly reduce aldehydes and ketones to the corresponding alcohols in high efficiency and selectivity under mild conditions. There are little steric and electronic effects on this reduction.

A method for the production of sulfate or sulfonate esters

The present invention relates to method for the production of sulfate or sulfonate esters essentially comprising the steps of adding sulfuric acid or sulfonic acid to boron acid in a medium with or without solvent (121), stirring the prepared mixture 8122), removing the precipitated boric acid (123), removing the solvent in case the solvent is used (124), producing dialkyl sulfate esters, mono alkyl sulfate esters and sulfonate esters of alkali metal salts (125), and based on the acidolysis of boron esters obtained from alcohol and boric acid with sulfuric acid or sulfonic acid.

Ammonia borane as a metal free reductant for ketones and aldehydes: A mechanistic study

Without a catalyst ketones and aldehydes were reacted in THF with ammonia borane (AB) to proceed hydroboration forming alkyl borates. Mechanistic studies revealed that dissociation of ammonia from AB occurred before the hydroboration step. When methanol was used as the solvent, metal free methanolysis of AB would take place with the ketone/aldehyde being directly hydrogenated by the MeOH·BH3 complex.

Aliphatic thioethers by s-alkylation of thiols via trialkyl borates

A simple and convenient one-pot procedure is described for the synthesis of thioethers via boron esters. This procedure involves in-situ generation of alkyl sulfates by reaction of trialkyl borates with concentrated sulfuric acid and subsequent reaction with thiols in the presence of pyridine. The reactions with boron esters of primary or secondary alcohols proceed cleanly at 100C and afford aliphatic thioethers in reasonable yields (59-93%) within 24 h. Interestingly, the 1H NMR spectra of the products showed no sign of positional isomerisms. The method fails however with thiophenol and does not yield aromatic thioethers, due to electrophilic substitution at the phenyl ring. Copyright Taylor & Francis Group, LLC.

Practical and efficient procedure for the in situ preparation of B-alkoxyoxazaborolidines. Enantioselective reduction of prochiral ketones

A new method for the in situ elaboration of B-alkoxyoxazaborolidines is presented. Their use in the enantioselective reduction of prochiral aromatic ketones provides excellent chemical and optical yields of chiral alcohols.

Process for preparing aldehydes from oxirane compounds

Aldehydes are prepared by reacting an oxirane compound with hydrogen peroxide in the presence of a boron compound.