51861-23-5Relevant articles and documents
Pd-catalyzed thiocarbamoylation of terminal alkynes with sulfenamide and carbon monoxide
Kuniyasu, Hitoshi,Kato, Tomohiro,Asano, Shigehito,Ye, Jia-Hai,Ohmori, Takumi,Morita, Masaki,Hiraike, Hiroshi,Fujiwara, Shin-Ichi,Terao, Jun,Kurosawa, Hideo,Kambe, Nobuaki
, p. 1141 - 1144 (2006)
Regio- and stereoselective thiocarbamoylation of terminal alkynes successfully took place using 2,4,5-tri-Cl-C6H2SNEt 2 as a reaction substrate and PdCl2(PPh3) 2/PPh3/n-Bu4
Palladium-catalyzed insertion reactions of isocyanides into thiocarbamates and selenocarbamates
Shiro, Daisuke,Fujiwara, Shin-Ichi,Tsuda, Susumu,Iwasaki, Takanori,Kuniyasu, Hitoshi,Kambe, Nobuaki
supporting information, p. 465 - 467 (2015/05/20)
The insertion reaction of isocyanides with thiocarbamates and selenocarbamates in the presence of a Pd(0) catalyst to selectively give 2-oxoethanimidothioates and -selenoates is reported. This is the first example of the insertion of an isocyanide into a
A facile method for the synthesis of thiocarbamates: Palladium-catalyzed reaction of disulfide, amine, and carbon monoxide
Nishiyama, Yutaka,Kawamatsu, Hiroaki,Sonoda, Noboru
, p. 2551 - 2554 (2007/10/03)
(Equation Presented) A new method for the synthesis of thiocarbamates has been developed. When dialkyl or diaryl disulfides were allowed to react with secondary amines and carbon monoxide in the presence of a catalytic amount of a palladium complex, the thiocarbamates were obtained in moderate to good yields. In contrast to that of secondary amines, in the reaction of a primary amine, no formation of thiocarbamate was confirmed, but urea was formed in good yield.
