51869-34-2

Basic information

• Product Name: methyl α-L-ristosaminide hydrochloride
• Synonyms: methyl α-L-ristosaminide hydrochloride
• CAS NO: 51869-34-2
• Molecular Weight: 197.662
• Mol File: 51869-34-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl α-L-ristosaminide hydrochloride(CAS DataBase Reference)
• NIST Chemistry Reference: methyl α-L-ristosaminide hydrochloride(51869-34-2)
• EPA Substance Registry System: methyl α-L-ristosaminide hydrochloride(51869-34-2)

Safety Data

• Hazardous Substances Data: 51869-34-2(Hazardous Substances Data)

Upstream product

• 89128-75-6 methyl 3-amino-2,3,6-trideoxy-2-iodo-α-DL-galactopyranoside hydrochloride 
• 26922-36-1 methyl 2,3,6-trideoxy-α-DL-erythro-hex-2-enopyranoside 
• 89128-75-6 methyl 3-amino-2,3,6-trideoxy-2-iodo-α-DL-altropyranoside hydrochloride 
• 83803-05-8 2,3,4,6-tetradeoxy-4',5'-dihydro-2-iodo-2'-trichloromethyl(methyl α-DL-altropyranosido)<3,4-d>oxazole 
• 83803-03-6 methyl 2,3,6-trideoxy-4-O-trichloroacetimidoyl-α-DL-erythro-hex-2-enopyranoside 
• 4208-64-4 1-(2-furyl)ethanol 
• 33647-82-4 methyl 2,3,6-trideoxy-α-DL-glycero-hex-2-enopyranosid-4-ulose 
• 33647-67-5 1-(2,5-dimethoxy-2,5-dihydrofuran-2-yl)ethanol from 2-Acetylfuran 
• 1192-62-7 1-(2-furyl)-1-ethanone 

Downstream Products

• 109978-55-4 Methyl-3-<(benzyloxycarbonyl)amino>-2,3,6-tridesoxy-α-L-erythro-hexopyranosid-4-ulose 
• 67758-45-6 methyl di-N,O-benzoyl-α-L-ristosaminide 
• 51869-35-3 methyl N,O-diacetylristosaminide 
• 87357-51-5 Methyl-3-<(benzyloxycarbonyl)amino>-2,3,6-tridesoxy-α-L-ribo-hexopyranosid 

Relevant articles and documents

SYNTHESIS OF (L)-DAUNOSAMINE AND RELATED AMINO SUGARS

1-(2-Furyl)ethanol (6) has been converted into methyl (+/-)-daunosaminide (1) and methyl (+/-)-ristosaminide (3) by use of an intramolecular cyclisation of a trichloroacetimidate group. (+/-)-Daunosamine (1) has been obtained more directly from the alcohol (10) by use of a modified Mitsunobu reaction; the scope of the latter reaction has been explored using cyclohex-2-en-1-ol as a model substrate.Asymmetric reduction of 2-acetylfuran (5) has given (S)-1-(2-furyl)ethanol (46) in good enantiomeric excess, thus providing a short route to the L-enantiomers of the amino sugars (1), (2), and (3) from a cheap, non-carbohydrate precursor.