51907-90-5Relevant academic research and scientific papers
Oxidative heck-type reaction involving cleavage of a carbon-phosphorus bond of arylphosphonic acids
Inoue, Atsushi,Shinokubo, Hiroshi,Oshima, Koichiro
, p. 1484 - 1485 (2003)
Cleavage of a carbon-phosphorus bond is achieved under palladium catalysis in an oxidative Heck-type reaction which exploits arylphosphonic acids. The reaction of arylphosphonic acids with alkenes provides arylation products in good yields in the presence of TBAF with trimethylamine oxide as an oxidant. Copyright
Preparation of Unsubstituted and Chlorine-Carrying phosphonic Acids by a Modified Doak-Freedman Procedure
Klumpp, Egon,Eifert, Gyula,Boros, Peter,Szulagyi, Janos,Tamas, Jozsef,Czira, Gabor
, p. 2021 - 2022 (2007/10/02)
The performance of cuprous chloride and different phase-transfer catalysts using the Doak-Freedman procedure for preparing aromatic phosphonic acids have been compared by measurements of the evolved nitrogen volume in an eudiometer tube.In the investigate
SYNTHESIS OF PHOSPHONIC DICHLORIDES AND CORRELATION OF THEIR P-31 CHEMICAL SHIFTS
Grabiak, Raymond C.,Miles, James A.,Schwenzer, Gretchen M.
, p. 197 - 202 (2007/10/02)
Various mono-substituted diethyl arylphosphonates were prepared in good yield by treatment of aryl bromides or iodides with triethyl phosphite in the presence of NiCl2 or alternatively, addition of the aryl grignard reagent to diethyl phosphorochloridate.
