5198-68-5Relevant academic research and scientific papers
Metal-Free Br?nsted Acid-Catalyzed Rearrangement of δ-Hydroxyalkynones to 2,3-Dihydro-4 H-pyran-4-ones: Total Synthesis of Obolactone and a Catechol Pyran Isolated from Plectranthus sylvestris
Gholap, Sachin P.,Jangid, Dashrath,Fernandes, Rodney A.
, (2019/03/19)
A metal-free, Br?nsted acid, pTsOH-catalyzed intramolecular rearrangement of δ-hydroxyalkynones to substituted 2,3-dihydro-4H-pyran-4-ones was developed. The rearrangement occurs with high regioselectivity under mild and open-air conditions. The scope of work was illustrated by synthesizing an array of aliphatic and aromatic substituted 2,3-dihydro-4H-pyran-4-ones in up to 96% yield, 100% atom economy, and complete regioselectivity. Some of the dihydropyranones are utilized for vinylic halogenations and to complete the total synthesis of bioactive natural products, obolactone and a catechol pyran isolated from Plectranthus sylvestris (Labiatae).
Highly efficient mesoporous polymer supported phosphine-gold(i) complex catalysts for amination of allylic alcohols and intramolecular cyclization reactions
Gu, Huoliang,Sun, Xiong,Wang, Yong,Wu, Haihong,Wu, Peng
, p. 1737 - 1743 (2018/02/06)
A series of novel heterogeneous gold(i) catalysts were synthesized by immobilizing gold(i) complexes on ordered mesoporous polymer FDU-15 and characterized by XRD, N2 adsorption-desorption, FT-IR, TEM, EDS, etc. The catalytic activities of thes
Cationic gold(I)-catalyzed intramolecular cyclization of γ-hydroxyalkynones into 3(2H)-furanones
Egi, Masahiro,Azechi, Kenji,Saneto, Moriaki,Shimizu, Kaori,Akai, Shuji
supporting information; experimental part, p. 2123 - 2126 (2010/06/12)
"Chemical Equation Presented" The combination of (p-CF 3C6H4)3PAuCl and AgOTf generates a powerful catalyst for the intramolecular cyclizations of readily available y-hydroxyalkynones un-der mild conditions. The
