52056-02-7Relevant academic research and scientific papers
Synthesis of Organolithium Compounds from Phenyl Selenides
Krief, Alain,Nazih, Abdesslame,Hobe, Myriam
, p. 8111 - 8114 (2007/10/02)
Alkyl aryl selenides react with lithium arenides to produce, regioselectively, alkyllithiums and lithium arylselenolates.Experimental conditions, especially the temperature, have a profound effect on the course of this reaction and on the nature of the products.
ORGANOSELENIUM COMPOUNDS VII. METHODS OF CONTROLLING THE REACTION OF ORGANIC HALIDES WITH MAGNESIUM AND SELENIUM
Nedugov, A. N.,Pavlova, N. N.,Lapkin, I. I.
, p. 1829 - 1832 (2007/10/02)
The action of aryl bromides on a mixture of magnesium and selenium in ether in ratios of 1.5-2:1:1 leads to diaryl selenides and bis(bromomagnesium) selenide, which gives organic selenides with electrophiles.The reaction of Grignard reagents with an excess of selenium (ArBr:Mg:Se ratios of 1:1:1.5) in ether leads to diaryl diselenides, while the reaction in THF leads to a mixture of polyselenides and diaryl diselenides.
