52066-61-2Relevant academic research and scientific papers
Thermally activated delayed fluorescent material based on 9,10-dihydro-9,9-dimethylacridine analogues for prolonging device longevity
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Page/Page column 214-216, (2022/02/16)
Thermally activated delayed fluorescent compounds and uses thereof are described. The thermally activated delayed fluorescent compounds are an analogues of 9,10-dihydro-9,9-dimethylacridine compounds.
Novel compounds for organic electronic material and organic electronic device using the same
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Paragraph 0280; 0281; 0284; 0285, (2016/10/08)
The present invention refers to novel organic for electronic material containing the same compound and relates to organic electronic devices, particularly for electronic material organic the present invention according to formula 1 or formula 2 compound i
The Chemistry of 5,6,7,12-Tetrahydro-5,7-dioxo-N-phenyldibenzazocine: A New Entry in the Dibenzazocine Class
Fox, John L.,Chen, Chin H.,Luss, Henry R.
, p. 2980 - 2983 (2007/10/02)
5,6,7,12-Tetrahydro-5,7-dioxo-N-phenyldibenzazocine was isolated as a byproduct of the methylation of the sterically hindered 2,2'-dicarbomethoxytriphenylamine.The isolation, chemical and physical characterization and single-crystal X-ray structure o
Modified Tetrahelicene Systems, III: Doubly ortho-Bridged Triphenylamine Derivatives
Hellwinkel, Dieter,Schmidt, Werner
, p. 358 - 384 (2007/10/02)
The heterocyclic (2a, b, 19, 3b-f, and 9a-c) as well as the carbocyclic naphthanthracene derivatives (21-23), which can be represented by the skeleton types A and B (table 2), are helically distorted in the stereochemical ground state.They racemize so fast, however, that their free enthalpies of racemization (ΔG* * 21 (88) kcal(kJ)/mol) could be determined by standard DNMR methods.Only derivatives of compound type 3 with relatively large bridge Y (3a, Y = C(CH3)2, 3g', Y = S) exhibit higher racemization barriers (ΔG*160 = 24 (100.4) and 28.4 (119) kcal(kJ)/mol), which had to be evaluated by classical equilibration procedures.With the results obtained in this way the working hypothesis has been confirmed, according to which for compounds A and B enlargement of the bridges Y and/or X, as well as diminution of the center Z - in holding the periphery constant - should lead to an increase of nonbonding interactions in the planar transition state and therefore to an increase of the racemization barrier.It has furthermore been shown with numerous substitution products of compound type 1 that here frequently accidental coincidences of the 1H NMR signals of diastereotopic and also constitutopic groups do occur.
