52087-18-0

Upstream product

• 33803-58-6 1-(triphenylphosphoranylidene)-2-heptanone 
• 52087-15-7 3-formyl-2-(7-hydroxyheptyl)-5(2-tetrahydropyranyloxy)cyclopentanol 
• 52087-14-6 2-(7-acetoxyheptyl)-3-oxo-4-(tetrahydropyran-2-yloxy)cyclopentanecarbonitrile 
• 52087-11-3 1-(7-Hydroxy-heptyl)-6-oxa-bicyclo[3.1.0]hexan-2-one 
• 110-87-2 3,4-dihydro-2H-pyran 
• 52087-13-5 2-(7-acetoxyheptyl)-3-cyano-5-hydroxycyclopentanone 
• 52087-12-4 5-acetoxy-2-(7-acetoxyheptyl)cyclopent-2-enone 
• 33803-57-5 2-(7-hydroxyheptyl)-2-cyclopenten-1-one 

Downstream Products

• 52087-30-6 7-[(1S,3R,5S)-3-Hydroxy-2-oxo-5-((E)-3-oxo-oct-1-enyl)-cyclopentyl]-heptanoic acid 
• 52087-30-6 7-[(1S,3S,5S)-3-Hydroxy-2-oxo-5-((E)-3-oxo-oct-1-enyl)-cyclopentyl]-heptanoic acid 

Relevant academic research and scientific papers

Prostaglandins Part 7. Synthesis of (+/-)-11-Deoxy-10-hydroxy- and (+/-)-11-Deoxy-10-oxoprostaglandins

The epoxides of 2-alkylcyclopent-2-enones (I) react with acetic acid to give 5-acetoxy-2-alkylcyclopent-2-enones (II) which afford (+/-)-11-deoxy-10-hydroxyprostaglandins via conjugate-addition reactions.The 11-deoxy-10-hydroxyprostaglandin (IXa) readily undergoes base-catalysed autoxidation to the 11-deoxy-10-oxoprostaglandin (XIII).