521068-33-7Relevant academic research and scientific papers
A novel and simple procedure for the enantiospecific synthesis of bridgehead norbornane thioethers and thiocyanates
Garcia Martinez, Antonio,Teso Vilar, Enrique,Moreno Jimenez, Florencio,Alvarez Garcia, Ana Maria,Pinilla Rodriguez, Patricia
, p. 2635 - 2639 (2007/10/03)
An easy three-step route for the enantiospecific synthesis of novel 1-norbornyl thioethers and thiocyanates from readily available natural fenchone and camphor is described. The key step of the synthetic route is the nucleophilic substitution over the sulfenyl sulfur atom of the intermediate thiotriflates by the corresponding C-nucleophiles.
