52126-52-0Relevant academic research and scientific papers
Unexpected conversions of selected heteroorganic compounds
Drabowicz, Jozef
, p. 437 - 442 (2002)
A few unexpected conversions of selected heteroorganic compounds are described, including the formation of N-sulfonyl sulfenamide derivatives and the mixed phosphinyl-sulfenyl anhydrides in the reactions of sulfinyl chlorides with α-phenylethylamine or t-butyl-phenylphosphine oxide, respectively. Unexpected reactions of the ortho hydroxyalkyl-substituted diaryl sulfoxides and hypervalent sulfur and selenium derivatives, induced by triphenylphosphine, are also presented. Attempts to rationalize the observed reaction courses are briefly discussed.
