Heteroatom Chemistry p. 437 - 442 (2002)
Update date:2022-08-04
Topics:
Drabowicz, Jozef
A few unexpected conversions of selected heteroorganic compounds are described, including the formation of N-sulfonyl sulfenamide derivatives and the mixed phosphinyl-sulfenyl anhydrides in the reactions of sulfinyl chlorides with α-phenylethylamine or t-butyl-phenylphosphine oxide, respectively. Unexpected reactions of the ortho hydroxyalkyl-substituted diaryl sulfoxides and hypervalent sulfur and selenium derivatives, induced by triphenylphosphine, are also presented. Attempts to rationalize the observed reaction courses are briefly discussed.
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