5215-63-4Relevant academic research and scientific papers
Microwave-Enhanced Coupling of Carboxylic Acids with Liquid Ketones and Cyclic Ethers Using Tetrabutylammonium Iodide/ t-Butyl Hydroperoxide
Macías-Benítez, Pablo,Moreno-Dorado, F. Javier,Guerra, Francisco M.
, p. 6027 - 6043 (2020/05/22)
The oxidative coupling of carboxylic acids with liquid ketones and cyclic ethers has been accomplished in minutes using t-butyl hydroperoxide in the presence of tetrabutylammonium iodide under microwave irradiation in the absence of a solvent. In addition to drastically shortening the reaction times, the use of microwaves resulted, in general, in yields equal to or higher than those obtained by conventional heating.
Rearrangement of 2-bromo-1-(bromomethyl)ethyl esters under basic conditions: Scope and mechanism
Alliot, Julien,Gravel, Edmond,Doris, Eric
, p. 2861 - 2866 (2013/10/22)
A novel rearrangement of 2-bromo-1-(bromomethyl)ethyl esters into the corresponding 2-oxopropyl derivatives is reported. The mechanism of this transformation was studied by means of 18O- and 2H- labeling experiments. The reaction pro
Polymer supported reagents: Facile synthesis of β-oxalkyl (acetonyl) esters of carboxylic acids
Salunkhe, Manikrao M.,Sande, Amirhamja R.,Kanade, Annappa S.,Wadgaonkar, Prakash P.
, p. 2885 - 2891 (2007/10/03)
β-Oxoalkyl (acetonyl) esters have been synthesised in high yields and in a state of purity by reaction of chloroacetone with insoluble polymer supported carboxylate ions at room temperature.
