52158-22-2Relevant academic research and scientific papers
CONCURRENT LITHIATION OF COMPOUNDS CONTAINING -CH=CFCl AND -CF=CFH GROUPS
Yagupol'skii, L. M.,Cherednichenko, P. G.,Kremlev, M. M.
, p. 246 - 248 (2007/10/02)
The concurrent substitution of the hydrogen and chlorine atoms in α,β-difluorostyrene, α,β-difluoro-β-chlorostyrene, and 1,2-difluoro-1-chloroethene was studied.It was shown that the hydrogen and chlorine atoms in α,β-difluorostyrenes are substituted by l
Di- and Trifluorovinyllithium Reagents
Gillet, J. P.,Sauvetre, R.,Normant, J. F.
, p. 355 - 360 (2007/10/02)
We describe the preparation of trifluorovinyllithium (from chlorotrifluoroethylene in ether) and of (E)- and (Z)-1,2-difluorovinyllithiums.These reagents present useful synthons on the way to α,β-difluoro-α,β-unsaturated alcohols and acids as either (E)- or (Z)-isomers, and to β,γ(or γ,δ)-difluoro β,γ(or γ,δ)-unsaturated alcohols.
