52220-93-6Relevant academic research and scientific papers
A bromine-catalysed free-radical oxidation of acetamides from primary and secondary alkylamines by H2O2
Bjorsvik,Fontana,Liguori,Minisci
, p. 523 - 524 (2007/10/03)
New procedures based on the oxidation by bromine-catalysed hydrogen peroxide in a two-phase system provide simple and cheap transformations of alkylamines to carbonyl derivatives (aldehydes, ketones, carboxylic acid, imides, lactams) through the corresponding acetamides.
The Nature of the Transition State in Amides Pyrolysis. The Rates of Pyrolysis of N-benzoyl and N-acetylpropanamide, N-benzoyl and N-acetyl-2-methylpropanamide, and N-thioacetylpropanamide
Al-Awadi, Nouria A.,Al-Omran, Fatima A.,Mathew, Tommy
, p. 1 - 6 (2007/10/02)
The rates of gas-phase elimination reactions of N-benzoyl and N-acetyl-propanamide and N-benzoyl and N-acetyl-2-methylpropanamide are measured and discussed.They undergo unimolecular first-order elimination reactions.The reactivities of N-benzoylamides have been compared with each other and with those of N-acetylamides.The kinetic data together with the product analysis reveals that, the statistical factor of the availability of β-hydrogen atoms for elimination as well as steric factor are obscured by polar factor in gas-phase elimination reactions of N-benzoylamides while the statistical factor rather than electronic effect operates in each of N-acetylamides.
