52260-59-0Relevant academic research and scientific papers
Kinetic studies on the reaction of sulfinic acids with conjugated alkenes: IV. Kinetics of the addition of arenesulfinic acids to 2-nitro-1-phenyl-1-phenylsulfonylethene
Ivanova,Aleksiev
, p. 1015 - 1019 (2007/10/03)
The addition of unsubstituted and substituted benzenesulfinic acids to 2-nitro-1-phenyl-1-phenylsulfonylethene was studied kinetically by means of LC. The reaction follows the second-order kinetics: v = k[2-nitro-1-phenyl-1-phenylsulfonylethene] · [sulfinic acid]. The dependance of the rate constants on the temperature, and the influence of the p-substituents on the kinetic parameters were studied. The activation energy and the enthalpy of activation were calculated in the temperature range 288-308 K.
