52323-95-2

Basic information

• Product Name: t-butyl-t-butoxy nitroxide
• Synonyms: t-butyl-t-butoxy nitroxide
• CAS NO: 52323-95-2
• Molecular Weight: 160.236
• Mol File: 52323-95-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: t-butyl-t-butoxy nitroxide(CAS DataBase Reference)
• NIST Chemistry Reference: t-butyl-t-butoxy nitroxide(52323-95-2)
• EPA Substance Registry System: t-butyl-t-butoxy nitroxide(52323-95-2)

Safety Data

• Hazardous Substances Data: 52323-95-2(Hazardous Substances Data)

Upstream product

• 917-95-3 t-butylnitrite 
• 691-57-6 2-azidopropane 
• 14976-54-6 di-tert-butoxydiazene 
• 622-79-7 benzyl azide 
• 594-70-7 2-Methyl-2-nitropropane 

Relevant articles and documents

Trans-1,2-Disiloxybenzocyclobutene, an adequate partner for the auto-oxidation: EPR/spin trapping and theoretical studies

The auto-oxidation of trans-1,2-disiloxybenzocyclobutene 1 was found to be very efficient, giving endo-peroxide 7 in quantitative yield. Each step of the mechanism of spin-forbidden addition of triplet oxygen O2( 3Σg) was

Reactions of Ozonate and Superoxide Radical Anions

Potassium ozonate has been prepared by reaction of ozone with potassium superoxide dispersed in Freon-12.Orange solutions of potassium ozonate in benzene or toluene containing 18-crown-6 react with nitrone traps to give spin adducts mainly derived from the oxide radical anion, which is a decomposition product of the ozonate radical anion.With 2-methyl-2-nitrosopropane in toluene solution the ozonate gives five nitroxide radicals in whose formation the oxide radical anion is again implicated.With nitrosobenzene electron transfer occurs.Comparable reactions with superoxide are described.