t-butyl-t-butoxy nitroxide

Base Information

• Chemical Name: t-butyl-t-butoxy nitroxide
• CAS No.: 52323-95-2
• Molecular Formula: C₈H₁₈NO₂
• Molecular Weight: 160.236
• Mol file: 52323-95-2.mol

Synonyms:t-butyl-t-butoxy nitroxide

Chemical Property of t-butyl-t-butoxy nitroxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of t-butyl-t-butoxy nitroxide

There total 5 articles about t-butyl-t-butoxy nitroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-bis(tert-butyldimethylsilyloxy)benzocyclobutene + t-butylnitrite (917-95-3) → di-tert-butyl nitroxide (2406-25-9,44871-19-4) + t-butyl-t-butoxy nitroxide (52323-95-2) + C24H44NO5Si2

Guidance literature:

With oxygen; In benzene; at 40 ℃; for 2h;

DOI:10.1039/c3cp55077j

Reference yield:

2-Methyl-2-nitropropane (594-70-7) → di-tert-butyl nitroxide (2406-25-9,44871-19-4) + t-butyl-t-butoxy nitroxide (52323-95-2) + C13H36NO2Si4 (124687-55-4) + C13H36NO3Si4 (137743-65-8)

Guidance literature:

With di-tert-butyl peroxide; tris-(trimethylsilyl)silane; In benzene; Further byproducts given; Ambient temperature; Irradiation;

DOI:10.1021/jo00029a029

Reference yield:

t-butylnitrite (917-95-3) → di-tert-butyl nitroxide (2406-25-9,44871-19-4) + t-butyl-t-butoxy nitroxide (52323-95-2) + N-tert-butyl-N-benzylnitroxyl (24293-08-1) + Benzyloxy-tert.butyl-aminyloxid (109492-49-1)

Guidance literature:

With 18-crown-6 ether; potassium ozonate; In toluene; at -50 - 0 ℃; Product distribution; with potassium superoxide, too;

DOI:10.1039/f19878300211

upstream raw materials:

t-butylnitrite

2-azidopropane

di-tert-butoxydiazene

benzyl azide