52406-33-4Relevant academic research and scientific papers
Synthesis of the Sex Pheromone of the Oleander Scale (Aspidiotus nerii)
Casta?eda, Mary Monta?o,Bargues, Javier Marzo,Primo, Jaime,Fuertes, Ismael Navarro
, p. 8578 - 8588 (2019)
A total synthesis of the oleander scale [Aspidiotus nerii (Bouche)] sex pheromone, the unique sesquiterpenoid containing a cyclobutane moiety of this class of compounds, has been developed. In order to implement this sex pheromone as a new environmentally
Using nucleophilic substitution reactions to understand how a remote alkyl or alkoxy substituent influences the conformation of eight-membered ring oxocarbenium ions
Chamberland, Stephen,Woerpel
, p. 4739 - 4741 (2007/10/03)
(Chemical Equation Presented) A remote alkoxy substituent strongly stabilizes one particular conformer of an eight-membered ring oxocarbenium ion by a through-space electrostatic effect. X-ray crystallographic analysis of a crystalline derivative proves t
Stereoselectivity of Electrophile-Promoted Cyclizations of γ-Hydroxyalkenes. An Investigation of Carbohydrate-Derived and Model Substrates
Reitz, Allen B.,Nortey, Samuel O.,Maryanoff, Bruce E.,Liotta, Dennis,Robert, Monahan
, p. 4191 - 4202 (2007/10/02)
We have investigated cyclization reactions of γ-hydroxyalkenes bearing an alkoxy or alkyl substituent on the allylic carbon.A variety of electrophiles N-bromosuccinimide, N-iodosuccinimide, iodine, mercury(II) acetate, mercury(II) trifluoroacetate, mercu
