52429-99-9Relevant academic research and scientific papers
Lead ion induced chemodosimeter approach of a tripodal hydroxyl-quinoline based phospho-ester through P-O bond cleavage
Sain, Dibyendu,Kumari, Chanda,Kumar, Ashish,Nayek, Hari Pada,Dey, Swapan
, p. 9187 - 9192 (2016/06/14)
Lead ion induced P-O bond breaking with instant colour change was observed in a tripodal hydroxyl-quinoline based phosphor-ester (HQP). A new penta-coordinated lead chelate complex [Pb4HQ6(ClO4)2] was found. The hydrolysis reaction followed by P-O bond cleavage with 'Pb-O' and 'Pb-N' bond formation proved the chemodosimeter approach.
PHOTOCHEMICAL REACTIONS OF TRI-1-NAPHTHYL AND TRIS(8-QUINOLYL) PHOSPHATES
Nakamura, Mitsunobu,Okamoto, Yoshiki,Takamuku, Setsuo
, p. 137 - 144 (2007/10/03)
Upon UV-irradiation in alcohol, tri-1-naphthyl phosphate give 1-naphthyl 1,2'-binaphthalene-1'-yl phosphate and 1,1'-binaphthalene through intramolecular processes.Under the same conditions, tris(8-quinolyl) phosphate give alkyl phosphates by photo-alcoholysis, but in acetonitrile furadiquinoline was given.The reaction mechanisms was investigated by means of quenching experiments for fluorescence spectra and products by oxygen. - Key words: Tri-1-naphthyl phosphate; tris(8-quinolyl) phosphate; reaction mechanism; fluorescence spectra; UV spectra
