52586-63-7

Upstream product

• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 

Downstream Products

• 28310-00-1 cis-dibromo[1,1'-ethanebis[1,1-diphenylphosphine-κP]]platinum 
• 903897-55-2 [PtBr(C₆H₄F)(dppe)] 
• 903897-59-6 trans-[PtBr₂(C₆H₄F)2(dppe)] 
• 83095-83-4 [platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] 
• 903897-51-8 [PtI(C₆H₄F)(dppe)] 

Relevant academic research and scientific papers

UEBER DEN MECHANISMUS DER LICHT-INDUZIERTEN ELIMINIERUNG DES BIPHENYL-SYSTEMS AUS cis-BIS(PHENYL)PLATIN(II)-VERBINDUNGEN

We report the light-induced reductive elimination of the biphenyl system from compounds of the types bis(phenyl)2-1,2-bis(diphenylphosphano)ethan>platinum(II), bis(phenyl)2-cis-1,2-bis(diphenylphosphano)ethene>platinum(II) and bis(phenyl)2-1,2-bis(diphenylphosphano)benzene>platinum(II) with substituents in the platinum-bound phenyl rings.The elimination proceeds via a concerted reaction mechanism without any observable free radical involvement.

Synthesis of Platinum(II) Alkyl and Aryl Complexes from K2 and Tetraorganotin Compounds in Dimethyl Sulphoxide

Complexes cis- and cis-(dmso=dimethyl sulphoxide) are readily obtained from K2 and SnMe3R (R=aryl or Me) in dmso at 70-90 deg C.Hydrogen-1 n.m.r. spectra show that the dmso ligands are bound through sulphur in solution an