903897-55-2Relevant academic research and scientific papers
Aryl-halide versus aryl-aryl reductive elimination in Pt(IV)-phosphine complexes
Yahav-Levi, Anette,Goldberg, Israel,Vigalok, Arkadi
, p. 8710 - 8711 (2007/10/03)
Upon the addition of Br2 to complexes (P-P)Pt(Ar)2, two different products were observed, depending on the bite angle of the bidentate phosphine ligand: a Pt(II) aryl bromide complex, the product of C-Br reductive elimination, and Pt(IV) oxidative addition complex. At high temperatures, the latter exclusively gave the product of the C-C reductive elimination. Copyright
