5259-31-4

Usage

Uses

6-Methyl-3-cyclohexene-1-methanol is used in preparation of Hydrocarbon detergent for printed circuit board.

InChI:InChI=1/C8H14O/c1-7-4-2-3-5-8(7)6-9/h2-3,7-9H,4-6H2,1H3

Upstream product

• 89-94-1 6-methyl-3-cyclohexene-1-carbaldehyde 
• 1215204-53-7 tert-butyldimethyl((6-methylcyclohex-3-enyl)methoxy)silane 
• 15111-54-3 methyl (1R,6R)-6-methylcyclohex-3-ene-1-carbooxylate 
• 89-94-1 trans-6-methyl-3-cyclohexene-1-carboxaldehyde 
• 555-31-7 aluminum isopropoxide 

Downstream Products

• 4854-91-5 4-Chloromethyl-5-methyl-cyclohexene 
• 3685-01-6 trans-4,5-dimethylcyclohexene 
• 5465-09-8 trans-1,2-dimethyl-cyclohexan-4-one 
• 70289-14-4 Δ³-Cyclohexen-carbinol-acetat 
• 4300-00-9 1,2-dimethylcyclohex-4-ene 
• 125975-54-4 Toluene-4-sulfonic acid 6-methyl-cyclohex-3-enylmethyl ester 
• 39155-46-9 phenyl-carbamic acid-(6-methyl-cyclohex-3-enylmethyl ester) 

Relevant academic research and scientific papers

A mild and chemoselective method for the deprotection of tert-butyldimethylsilyl (TBDMS) ethers using iron(III) tosylate as a catalyst

The most common method for the deprotection of TBDMS ethers utilizes stoichiometric amounts of tetrabutylammonium fluoride, n-Bu4N+F- (TBAF), which is highly corrosive and toxic. We have developed a mild and chemoselective method for the deprotection of TBDMS, TES, and TIPS ethers using iron(III) tosylate as a catalyst. Phenolic TBDMS ethers, TBDPS ethers and the BOC group are not affected under these conditions. Iron(III) tosylate is an inexpensive, commercially available, and non-corrosive reagent.

A Total Synthesis of (+/-)-Faranal, the True Trail Pheromone of Pharaoh's Ant, Monomorium pharaonis

A relatively short total synthesis of the true trail pheromone of Pharaoh's ant, (+/-)-faranal is reported.The carbon skeleton was assembled by a Wittig condensation between (Z)-6-methyloct-5-en-2-one (4) and the 5-carboxypentylphosphonium salt (15).The ketone (4) was prepared in 'one-pot' and in a stereoselective manner using vinyl cuprate chemistry, while the relative stereochemistry of the two methyl substituents in the phosphonium salt (15) was established by using the Diels-Alder adduct (16) of buta-1,3-diene and maleic anhydride, which, after reduction and oxidative cleavage of the resulting cis-1,2-dimethylcyclohex-4-ene (18), gave only meso-3,4-dimethyladipic acid (19); this in turn was converted into the salt (15) in six straight-forward steps.