5259-31-4

Basic information

• Product Name: 6-METHYL-3-CYCLOHEXENE-1-METHANOL
• Synonyms: 6-methyl-3-cyclohexene-1-methano;6-METHYL-3-CYCLOHEXENE-1-METHANOL;6-methylcyclohex-3-ene-1-methanol;(+/-)-6-METHYL-3-CYCLOHEXENE-1-METHANOL, 97%, MIXTURE OF CIS AND TRANS;6-methyl-3-cyclohexene-1-methanol, mixture of cis and trans;6-Methylcyclohex-3-enylmethanol
• CAS NO: 5259-31-4
• Molecular Formula: C₈H₁₄O
• Molecular Weight: 126.2
• EINECS: 226-063-6
• Product Categories: Alkenes;Cyclic;Organic Building Blocks
• Mol File: 5259-31-4.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 92-92.5℃ (10 Torr)
• Flash Point: 188 °F
• Appearance: /
• Density: 0.954 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.06 psi ( 20 °C)
• Refractive Index: n20/D 1.483(lit.)
• CAS DataBase Reference: 6-METHYL-3-CYCLOHEXENE-1-METHANOL(CAS DataBase Reference)
• NIST Chemistry Reference: 6-METHYL-3-CYCLOHEXENE-1-METHANOL(5259-31-4)
• EPA Substance Registry System: 6-METHYL-3-CYCLOHEXENE-1-METHANOL(5259-31-4)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 5259-31-4(Hazardous Substances Data)

Usage

Uses

6-Methyl-3-cyclohexene-1-methanol is used in preparation of Hydrocarbon detergent for printed circuit board.

InChI:InChI=1/C8H14O/c1-7-4-2-3-5-8(7)6-9/h2-3,7-9H,4-6H2,1H3

Upstream product

• 1215204-53-7 tert-butyldimethyl((6-methylcyclohex-3-enyl)methoxy)silane 
• 89-94-1 6-methyl-3-cyclohexene-1-carbaldehyde 
• 15111-54-3 methyl (1R,6R)-6-methylcyclohex-3-ene-1-carbooxylate 
• 555-31-7 aluminum isopropoxide 
• 89-94-1 trans-6-methyl-3-cyclohexene-1-carboxaldehyde 

Downstream Products

• 4854-91-5 4-Chloromethyl-5-methyl-cyclohexene 
• 5465-09-8 trans-1,2-dimethyl-cyclohexan-4-one 
• 4300-00-9 1,2-dimethylcyclohex-4-ene 
• 125975-54-4 Toluene-4-sulfonic acid 6-methyl-cyclohex-3-enylmethyl ester 
• 70289-14-4 Δ³-Cyclohexen-carbinol-acetat 
• 3685-01-6 trans-4,5-dimethylcyclohexene 
• 39155-46-9 phenyl-carbamic acid-(6-methyl-cyclohex-3-enylmethyl ester) 

Relevant articles and documents

A mild and chemoselective method for the deprotection of tert-butyldimethylsilyl (TBDMS) ethers using iron(III) tosylate as a catalyst

The most common method for the deprotection of TBDMS ethers utilizes stoichiometric amounts of tetrabutylammonium fluoride, n-Bu4N+F- (TBAF), which is highly corrosive and toxic. We have developed a mild and chemoselective method for the deprotection of TBDMS, TES, and TIPS ethers using iron(III) tosylate as a catalyst. Phenolic TBDMS ethers, TBDPS ethers and the BOC group are not affected under these conditions. Iron(III) tosylate is an inexpensive, commercially available, and non-corrosive reagent.

A total synthesis of (±)-Faranal, the true trail pheromone of Pharaoh's ant, Monomorium pharaonis

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