52594-52-2

Basic information

• Product Name: dimethyl(2,2'-bipyridine)platinum(II)
• Synonyms: dimethyl(2,2'-bipyridine)platinum(II)
• CAS NO: 52594-52-2
• Molecular Weight: 381.337
• Mol File: 52594-52-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dimethyl(2,2'-bipyridine)platinum(II)(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl(2,2'-bipyridine)platinum(II)(52594-52-2)
• EPA Substance Registry System: dimethyl(2,2'-bipyridine)platinum(II)(52594-52-2)

Safety Data

• Hazardous Substances Data: 52594-52-2(Hazardous Substances Data)

Downstream Products

• 115828-94-9 {platinum(Me)2(2,2'-bipyridine)Au(PPh₃)}NO₃ 
• 120610-82-4 Pt(CH₃)2(NC₅H₄)2OCOOCH(C₆H₅)CH₂ 
• 120709-21-9 Pt(CH₃)2(NC₅H₄)2OCOOCH(C₆H₅)CH₂ 
• 120610-84-6 Pt(CH₃)2(NC₅H₄)2OCOOCH(CH₂OC₆H₅)CH₂ 
• 120707-81-5 Pt(CH₃)2(NC₅H₄)2OCOOCH(CH₂OC₆H₅)CH₂ 
• 115828-96-1 {platinum(methyl)2(2,2'-bipyridine)silver(PPh₃)}BF₄ 
• 110173-75-6 PtCl(CH₃)2(CH₂AuP(OC₆H₅)3)((C₅H₄N)2) 
• 110173-73-4 PtCl(CH₃)2(CH₂AuP(C₆H₅)3)((C₅H₄N)2) 
• 315211-87-1 [PtMe₃(2,2'-bipy)(PMe₂Ph)][CF₃SO₃] 
• 315211-85-9 [PtMe₃(2,2'-bipy)(PMePh₂)][CF₃SO₃] 
• 1413947-07-5 [PtMe₂{κ²-O,O'-1,2-(O₂C)₂C₆H₄}(2,2'-bipyridine)] 
• 186321-16-4 [Pt(OH)(OMe)Me₂(2,2′-bipyridine)] 

Relevant articles and documents

Thermal decomposition of platinum(IV)-silicon, -germanium, and -tin complexes

The thermal decomposition of a number of complexes of the type [PtMe2(Me3E)X(diimine)] (E = Si, Ge, Sn; X = Cl, Br, I) has been studied. The thermal stability of complexes, as determined by thermogravimetric analysis (TGA), varies depending on the diimine ligand in the order 2,2′-bipyridyl (bpy) > 4,4′-di-tert-butyl-2,2′-bipyridyl (bpy-tbu2) > N-(2-(dimethylamino)ethyl)pyridine-2-aldimine (paen-me2) > (2-imino-n-propyl)pyridine (py-n-pr). Stability also varies according to the trends E = Sn ≈ Ge > Si and X = I > Br > Cl. The products of thermal decomposition have also been determined by 1H NMR and three distinct modes of decomposition are evident: reductive elimination of Me3EX, reductive elimination of Me4E, and α-elimination of Me2E. The competition between reductive elimination of Me3EX and Me4E depends primarily on the halide, X, with the ratio Me3EX:Me4E highest for X = Cl and lowest for X = I. The competition between reductive elimination and α-elimination depends primarily on E, with the tendency to α-elimination of Me2E increasing as E = Si 2(Me3Si)(bpy)] as 233 ± 14 kJ mol-1.