52613-84-0Relevant academic research and scientific papers
Thermochemical properties of palladium(II) chelates involving dialkyldithiocarbamates
Botelho,Souza,Nunes,Chagas,Garcia dos Santos,Da Conceicao,Dunstan
, p. 413 - 417 (2002)
Thermochemical properties of palladium(II) chelates involving diakyldithiocarbamates were studied using reaction-solution calorimetry. The homolytic and heterolytic mean palladium-sulphur bond-dissociation enthalpies were calculated using the standard mol
Kinetics of the thermal decomposition of bis(dialkyldithiocarbamate) of palladium(II) complexes in isothermal and nonisothermal conditions
Rangel, Jose Hilton G.,Francisco Oliveira, Severino,Espinola, Jose Geraldo P.,Gouveia Souza, Antonio
, p. 187 - 194 (2008/10/09)
Dialkyldithiocarbamate of palladium(II) complexes, Pd(S2CNR2)2, with R=C2H5, n-C3H7, n-C4H9, i-C4H9 and C5H11 were synthesized from the direct reaction of PdCl2 with corresponding amine and carbon disulphide. The complexes were characterized by the techniques of melting points, infrared absorption spectroscopy and mass spectrometry. The thermal decomposition reaction of complexes have been studied by isothermal and nonisothermal thermogravimetry. Superimposed curves of TG/DTG/DSC show that these reactions occur in the liquid phase. The kinetic isothermal model that best adjusted the experiment data were the R1 model.
