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α-Phenyl-α-styryl-oxirane, also known as 1-phenyl-1-(2-phenylethenyl)oxirane, is an organic compound characterized by a unique structure that includes a phenyl group (C6H5), a vinyl group (C2H3), and an oxirane (epoxy) ring. This molecule is a derivative of styrene, where one of the hydrogen atoms on the vinyl group is replaced by a phenyl group, and the double bond is involved in the formation of the three-membered oxirane ring. The compound is of interest in organic chemistry due to its potential applications in the synthesis of various pharmaceuticals and materials. It is also notable for its rigid structure and the possibility of engaging in π-π stacking interactions due to the presence of the phenyl rings. The compound's properties, such as reactivity and stability, are influenced by the electron-donating or electron-withdrawing nature of the substituents on the phenyl rings, making it a subject of study for understanding the effects of steric and electronic factors on chemical behavior.

52695-40-6

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52695-40-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 52695-40-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,2,6,9 and 5 respectively; the second part has 2 digits, 4 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 52695-40:
(7*5)+(6*2)+(5*6)+(4*9)+(3*5)+(2*4)+(1*0)=136
136 % 10 = 6
So 52695-40-6 is a valid CAS Registry Number.

52695-40-6Downstream Products

52695-40-6Relevant academic research and scientific papers

Efficient catalytic Corey-Chaykovsky reactions involving ketone substrates

Kavanagh, Sarah A.,Piccinini, Alessandro,Connon, Stephen J.

supporting information; experimental part, p. 2089 - 2093 (2010/11/04)

It has been demonstrated for the first time that a sulfide catalyst, utilised at 20 mol% loading, can promote methylene transfer to ketones in the presence of methyl triflate and an organic base. This metal-free methodology is of broad scope-both aliphatic and aromatic ketones (including trifluoromethyl ketones) can be converted to synthetically useful terminal epoxides in excellent yields at room temperature.

Reaction of diphenylsulfonium methylide with carbonyl compounds in non-basic media

Hioki,Tani,Sato

, p. 649 - 650 (2007/10/02)

Diphenylsulfonium methylide was formed by fluoride-induced desilylation of diphenyl[(trimethylsilyl)methyl]sulfonium triflate with cesium fluoride in dimethyl sulfoxide and allowed to react with carbonyl compounds in situ to give oxiranes.

TRIMETHYLSULFONIUM METHYLSULFATE, A SIMPLE AND EFFICIENT EPOXIDIZING AGENT.

Mosset, Paul,Gree, Rene

, p. 749 - 758 (2007/10/02)

Sulfonium salts 1 and 3 are highly reactive epoxidizing agents under phase transfer catalytic conditions.

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