52703-94-3Relevant academic research and scientific papers
A Reaction of Triazoles with Thioesters to Produce β-Sulfanyl Enamides by Insertion of an Enamine Moiety into the Sulfur-Carbonyl Bond
Miura, Tomoya,Fujimoto, Yoshikazu,Funakoshi, Yuuta,Murakami, Masahiro
, p. 9967 - 9970 (2015)
N-Sulfonyl-1,2,3-triazoles react with thioesters in the presence of a rhodium(II) catalyst to produce β-sulfanyl enamides in a stereoselective manner. The reaction proceeds through generation of an α-imino rhodium carbene complex, nucleophilic addition of
