52748-97-7Relevant academic research and scientific papers
Synthesis and crystal structures of trans-dichlorobis{tri(2-methylphenyl) stibine}palladium(II) and trans-dibromobis{tri(2-methylphenyl)stibine} palladium(II)
Mentes, Ayfer,Fawcett, John
, p. 1279 - 1283 (2008/10/09)
Tri(2-methylphenyl)stibine reacts with [PdX2(cod)] or PdX 2 (X = Cl or Br) to give the trans-[PdX2{Sb(2-Me- C 6H4)3}2]. The single crystal X-ray structures of trans-[PdX2{Sb(2-Me-C6H4) 3}2] (X = Cl or Br) revealed that the palladium atom is a square planar environment with mutually trans-Sb(2-methylphenyl)3 ligands. Iodine analogous of complex can also be prepared from trans metallation reaction with sodium iodine.
