52755-94-9Relevant academic research and scientific papers
FOUR-COORDINATE BORON COMPOUNDS
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Page/Page column 29, (2016/11/21)
A compound having a four-coordinate boron atom to which is connected a first C3-C25 substituent, a second C3-C25 substituent and a bridging substituent comprising from eight to forty non-hydrogen atoms and havin
Simple heteroatom engineering for tuning the triplet energy of organometallic host materials for red, green and blue phosphorescent organic light-emitting diodes
Oh, Chan Seok,Lee, Chil Won,Lee, Jun Yeob
supporting information, p. 3875 - 3877 (2013/07/19)
Triplet energy tuning from 2.48 eV to 2.94 eV by just a simple change of heteroatom in the ligand structure of Be complexes was studied using azole based triplet host materials. Three Be organometallic host materials with azole type ligands were synthesized and could be used as the host materials from red to deep blue phosphorescent organic light-emitting diodes. High quantum efficiency was obtained in red, green, blue and deep blue devices using the Be complexes. In particular, a high quantum efficiency of 26.1% was achieved in blue phosphorescent organic light-emitting diodes.
Intramolecular catalysis of phosphodiester hydrolysis by two imidazoles
Orth, Elisa S.,Brandao, Tiago A.S.,Souza, Bruno S.,Pliego, Josefredo R.,Vaz, Boniek G.,Eberlin, Marcos N.,Kirby, Anthony J.,Nome, Faruk
supporting information; scheme or table, p. 8513 - 8523 (2010/08/05)
Two imidazole groups act together to catalyze the hydrolysis of the phosphodiester bis(2-(1-methyl-1H-imidazolyl)phenyl) phosphate (BMIPP). A full investigation involving searching computational and electrospray ionization (ESI-MS-/MS) and ultra mass spec
Intramolecular acid-base catalysis of a phosphate diester: Modeling the ribonuclease mechanism
Orth, Elisa S.,Brandao, Tiago A. S.,Milagre, Humberto M. S.,Eberlin, Marcos N.,Nome, Faruk
, p. 2436 - 2437 (2008/09/17)
The hydrolysis of the phosphate diester bis(2-(1-methyl-1H-imidazolyl)phenyl) phosphate BMIPP was evaluated as an intramolecular model for the ribonuclease A mechanism. Kinetic and thermodynamic data, isotope effects and ESI-MS and ESI-MS/MS analysis supp
Nickel/zinc-mediated alkyl carbon-oxygen bond cleavage of alkyl aryl ethers
Maeyama, Katsuya,Kobayashi, Masato,Yonezawa, Noriyuki
, p. 869 - 875 (2007/10/03)
Alkyl carbon-oxygen bonds of alkyl aryl ethers bearing suitable coordination sites were efficiently cleaved by treatment with nickel(II) chloride and zinc in p-xylene under neutral conditions.
