527684-35-1Relevant academic research and scientific papers
Facile C-N cleavage reactions of secondary and tertiary alkyl amines by P,O chelating rhodium and iridium complexes
Yamamoto, Yasuhiro,Seta, Jouji,Murooka, Hiroshi,Han, Xiao-Hong
, p. 202 - 205 (2003)
The reactions of Cp*MCl(MDMPP-P,O) (1: M = Rh; 3: M = Ir; MDMPP-P, O = PPh2(C6H3-2-O-6-MeO)) with secondary or tertiary alkyl amine (R2NH or R3N) in the presence of KPF6 underwent a C-N cleavage of amine to afford primary amine complex [Cp*M(MDMPP-P,O) (RNH2)](PF6) (2: M = Rh; 4: M = Ir).
