52776-35-9Relevant academic research and scientific papers
Regioselective synthesis of (trifluoromethyl)-β-chloroenones
Alvernhe, Gerard,Bensadat, Abdelkader,Ghobsi, Abdelkader,Laurent, Andre,Laurent, Eliane
, p. 169 - 172 (1997)
The regioselectivity of the conversion of 1,3-diketones into β-chloroenones can be changed by the appropriate choice of the reagent: reaction with "Vilsmeier's reagent" prepared from POCl3 and dimethylformamide or treatment of the diketone with the oxalyl chloride in the presence of dimethylformamide.
ACYLATION OF VINYL CHLORIDES BY CATIONOID COMPLEXES
Borodaev, S. V.,Zubkova, O. V.,Luk'yanov, S. M.
, p. 1662 - 1666 (2007/10/02)
Vinyl chlorides with various structures undergo acylation ny acylium hexachloroantimonates with the formation β-chlorovinyl, β-chloroallyl, and allenyl ketones.The acylation of vinyl chloride with a quaternary carbon atom at the allylic position gave 2,5-dihydro- and tetrahydrofurylium salts.
