528-15-4Relevant academic research and scientific papers
Preparation of functionalized aryl magnesium reagents by the addition of magnesium aryl thiolates and amides to arynes
Lin, Wenwei,Sapountzis, Ioannis,Knochel, Paul
, p. 4258 - 4261 (2007/10/03)
(Chemical Equation Presented) Reactive arynes, which are readily generated by the reaction of ortho-iocloarylsulfonates with iPrMgCl, undergo the smooth addition of various magnesium nucleophiles like magnesium thiolates, selenides, and amides. In all cases the resulting functionalized aryl magnesium species can be trapped by an electrophile leading to highly functionalized aromatic compounds (see scheme).
Iodination of Phenols by Use of Benzyltrimethylammonium Dichloroiodate(1-)
Kajigaeshi, Shoji,Kakinami, Takaaki,Yamasaki, Hiromichi,Fujisaki, Shizuo,Kondo, Manabu,Okamoto, Tsuyoshi
, p. 2109 - 2112 (2007/10/02)
The reaction of phenols with benzyltrimethylammonium dichloroiodate(1-) in dichloromethane-methanol in the presence of CaCO3 or NaHCO3 for several hours at room temperature gave iodophenols in good yields.
