52812-64-3Relevant academic research and scientific papers
Synthesis of substituted 2,3-dihydro-1H-boroles by transmetalation of aluminacyclopent-2-enes with BF3 · Et2O
Khafizova,Khusainova,Tyumkina,Dzhemilev
, p. 761 - 766 (2012)
A procedure was developed for selective synthesis of 4,5-dialkyl-1-fluoro- 2, 3-dihydro-1H-boroles via transmetalation of the corresponding aluminacyclopent-2-enes with BF3 · Et2O. 4,5-Dialkyl-1-fluoro-2,3-dihydro-1H-boroles were isolated as complexes with BEtF2. 4-Alkyl-5-dimethylaminomethyl-1-fluoro-2,3- dihydro-1H-boroles were synthesized for the first time.
