528598-36-9

Upstream product

• 100-39-0 benzyl bromide 
• 115114-87-9 (2R)-2-(2-benzyloxyethyl)oxirane 

Downstream Products

• 1307273-44-4 (2R,9S)-9,11-bis(benzyloxy)-2-[(tert-butyldiphenylsilyl)oxy]undec-6-yn-5-ol 
• 1307273-50-2 (2R,9S)-9,11-bis(benzyloxy)-2-hydroxyundec-6-yn-5-one 
• 1307273-45-5 (2R,9S)-2,9,11-tris(benzyloxy)undec-6-yn-5-ol 
• 1307273-46-6 (2R,9S)-9,11-bis(benzyloxy)-2-[(tert-butyldiphenylsilyl)oxy]undec-6-yn-5-one 
• 1307273-49-9 (2R,9S)-9,11-bis(benzyloxy)-2-hydroxyundecan-5-one 
• 1307273-48-8 (2R,9S)-9,11-bis(benzyloxy)-2-[(tert-butyldiphenylsilyl)oxy]undecan-5-one 
• 1307273-47-7 (2R,9S)-2,9,11-tris(benzyloxy)undec-6-yn-5-one 
• 528598-63-2 (S)-3-[(2R,8R,13R)-2-(tert-Butyl-diphenyl-silanyloxy)-13-((2R,5R,6R)-6-dodecyl-5-methoxymethoxy-tetrahydro-pyran-2-yl)-8,13-bis-methoxymethoxy-tridecyl]-5-methyl-5H-furan-2-one 
• 528598-62-1 (S)-3-[(Z)-(2R,8S,13R)-2-(tert-Butyl-diphenyl-silanyloxy)-13-((2R,5R,6R)-6-dodecyl-5-methoxymethoxy-tetrahydro-pyran-2-yl)-8,13-bis-methoxymethoxy-tridec-5-enyl]-5-methyl-5H-furan-2-one 
• 528598-55-2 (1R,6S)-8-(tert-Butyl-diphenyl-silanyloxy)-1-((2R,5R,6R)-6-dodecyl-5-methoxymethoxy-tetrahydro-pyran-2-yl)-octane-1,6-diol 
• 528598-52-9 (2R,3R,6R)-2-((E)-Dodec-2-enyl)-6-((1R,6S)-1,6,8-tris-benzyloxy-octyl)-tetrahydro-pyran-3-ol 
• 528598-67-6 (E)-3-[(1R,2R,7S)-2,7,9-Tris-benzyloxy-1-(2-[1,3]dithian-2-yl-ethyl)-nonyloxy]-acrylic acid ethyl ester 
• 528598-48-3 [(2R,3S,6R)-3-Hydroxy-6-((1R,6S)-1,6,8-tris-benzyloxy-octyl)-tetrahydro-pyran-2-yl]-acetic acid ethyl ester 
• 528598-50-7 [(2R,3S,6R)-3-Hydroxy-6-((1R,6S)-1,6,8-tris-benzyloxy-octyl)-tetrahydro-pyran-2-yl]-acetic acid 

Relevant academic research and scientific papers

An efficient convergent access to spiroketal segment of (+)-spiroxaline methyl ether

Starting from trimethylsilylacetylene, a facile synthesis of optically pure spiroketal unit of (+)-spiroxaline methyl ether has been described. The synthesis entails stepwise alkylation and acylation of an alkyne with two different readily available chira

Total synthesis of a cytotoxic acetogenin, pyranicin

(Matrix presented) The first total synthesis of a new cytotoxic acetogenin, pyranicin (1), is described. Sml2-induced reductive cyclization of β-alkoxy acrylate 4 proceeded stereoselectively to give 16,20-syn-19,20-trans-THP derivative 14, whic