52867-11-5

Upstream product

• 106-47-8 4-chloro-aniline 
• 63911-86-4 (4-Chloro-phenyl)-trimethylsilanyl-amine 
• 76541-52-1 N-(chlorosulfinyl)imidazole 
• 3005-50-3 N,N'-Thionyldiimidazole 
• 88693-68-9 trichloro-methanesulfenic acid-(4-chloro-anilide) 
• 119151-47-2 Trichlormethansulfinsaeure-<4-chlor-anilid> 

Downstream Products

• 20447-60-3 7-(4-chloro-phenyl)-3,3-dimethyl-8-thia-2,7-diaza-bicyclo[4.2.0]oct-1⁽⁶⁾-ene 8-oxide 
• 104577-42-6 2-(4-chloro-phenyl)-1-oxo-4,4-diphenyl-1λ⁴-[1,2]thiazetidin-3-one 
• 3815-52-9 3,4-bis-(4-chloro-phenyl)-3H-[1,2,3,5]oxathiadiazole 2-oxide 
• 63788-46-5 3-(4-chloro-phenyl)-2-oxo-6-phenyl-2,3-dihydro-2λ⁴-[1,2,3]oxathiazin-4-one 
• 962-08-3 N-(4-chlorophenyl)-3-oxo-3-phenylpropanamide 
• 10295-53-1 α-hydroxy-N-(4-chlorophenyl)phenylacetamide 
• 181651-29-6 N-(4-chlorophenyl)-N-methylethenesulfinamide 
• 181651-30-9 N-(4-chlorophenyl)-N-(trimethylsilyl)ethenesulfinamide 
• 139286-16-1 (E)-p-tolylethylenylsulphin-p-chloroanilide 
• 139286-18-3 (E)-p-chlorophenylethylenylsulphin-p-chloroanilide 
• 139286-15-0 diphenylethylenylsulphin-p-chloroanilide 
• 139286-20-7 (Z)-p-methoxyphenylethylenylsulphin-p-chloroanilide 
• 139286-17-2 (E)-p-methoxyphenylethylenylsulphin-p-chloroanilide 
• 13463-40-6 iron pentacarbonyl 

Relevant academic research and scientific papers

DI-2-PYRIDYL SULFITE. A NEW USEFUL REAGENT FOR THE PREPARATION OF N-SULFINYLAMINES, NITRILES, ISOCYANIDES, AND CARBODIIMIDES UNDER MILD CONDITIONS

Di-2-pyridyl sulfite is a very useful reagent for the preparation of N-sulfinylamines, nitriles, isocyanides, and carbodiimides in high yields under essentially neutral conditions.

Synthesis, characterization and vibrational studies of p-chlorosulfinylaniline

p-Cholorosulfinylaniline was prepared by the reaction of p-chloroaniline and SOCl2. The structural, conformational and configurational properties of the obtained liquid compound were studied by Raman and infrared spectroscopy in the liquid stat

Synthesis of benzo-ortho-thiazines S-oxides by diels-alder reaction of N-sulfinylanilines with norbornadiene

From substituted N-sulfinylanilines acting as dienes in the Diels-Alder reaction with norbornadiene S-oxides of benzo-ortho-thiazines were obtained, which were oxidized into the corresponding S,S-dioxides belonging to the class of hybrid thiazinesulfonami

N-heterocyclic carbene catalysis: Enantioselective formal [2+2] cycloaddition of ketenes and N-sulfinylanilines

Sultam of swing: Both enantiomers of 1,2-thiazetidin-3-one oxides were obtained in very good yields with excellent enantioselectivities when using N-heterocyclic carbene catalysts (see scheme; M.S.=molecular sieves, TBS=tert-butyldimethylsilyl). The products were easily converted into 3-oxo-β-sultams, α-mercapto amides, and β-mercapto amines through oxidation or reduction. Copyright

A-new synthesis of N-sulfinylamines via β-elimination of chloroform from trichloromethanesulfinamides

The synthesis of various N-monosubstituted trichloromethanesulfinamides by two alternative and novel procedures is described. All these compounds have been found to undergo base-induced elimination of chloroform with formation of the corresponding N-sulfinylamines. Reaction proceeds smoothly under mild conditions.

Substituted N-aryl alk-1-enesulfinamides: Preparation, properties and conversion into the corresponding indole compounds [1]

Reaction of vinylic organometallic derivatives with N-sulfinyl arenamines 2 affords the title sulfinamides 3. On heating their solutions in selected solvents to 80-124 °C, these sulfinamides are converted into the corresponding indoles 6, probably via a [3.3]-sigmatropic rearrangement to intermediates VIII which undergo an intramolecular carbophilic reaction of the nitrogen atom with the neighboring sulfine group, followed by elimination of HSOH. The triethyloxonium tetrafluoroborate- or boron trifluoride etherate catalyzed conversion 3 → 6 can be carried out at a much lower temperature. Elsevier,.

6?-Cycloadditions of Aryl and New Heteroaryl N-Sulphinylamines With 2,3-Dimethylbuta-1,3-diene: Synthesis, Kinetics, Substituent Effects, Theoretical Calculations, and Reaction Mechanism

A range of new N-sulphinylamine derivatives of heteroaryl rings, including tetrazoles, oxadiazoles, thiadiazoles, thiazoles, and oxazoles is reported.The influence of the -N=S+-O- group on the n.m.r. spectra of the ring to which it i

NEW FACILE SYNTHESIS OF N-SULFINYLAMINE DERIVATIVES USING N,N'-SULFINYLBISIMIDAZOLE AND N-(CHLOROSULFINYL)IMIDAZOLE

Treatment of amine derivatives such as amines, sulfonamides, and amides with N,N'-sulfinylbisimidazole (1) and N-(chlorosulfinyl)imidazole (2) in situ respectively gives the corresponding N-sulfinylamine derivatives (3): the latter reaction using N-(chlor

1,2-Thiazines and Related Heterocycles. Part 1. An Investigation of the Cycloadditions of N-Sulphinylanilines with 1,4-Epoxy-1,4-dihydronaphthalene and Other Alkenes

Evidence is adduced from the character of the alkenes which cycloadd to N-sulphinylanilines and from a kinetic investigation of the reactions of N-sulphinylanilines with 1,4-epoxy-1,4-dihydronaphthalene, examining the effects upon reaction rate of solvent polarity, temperature, and substitution in the N-sulphinylanilines, that the cycloadditions are pericyclic reactions of Diels-Alder type with inverse electron demand.A degree of charge separation in the transition state is indicated but this is small and confined essentially to the sulphinylaniline moiety.

Heterocyclic Synthesis with Malonyl Dichloride. Part 13. 6-Chloro-4-hydroxy-2-oxypyran-3-carboxanilides from N-Sulphinylanilines and Further Reactions of Malonyl Dichloride with Thiocyanates

N-Sulphinylanilines react with malonyl dichloride to give 6-chloro-4-hydroxy-2-oxopyran-3-carboxanilides with loss of the sulphoxide moiety as thionyl chloride.Milder conditions and electron-withdrawing substituents do not alter the course of the reaction of thiocyanates with malonyl dichloride to give 2-substituted-thio-7-chloro-4H,5H-pyranooxazine-4,5-diones.