52886-04-1Relevant academic research and scientific papers
Synthesis of (+)-Multifidene
Hemamalini, Sundarababu,Scheffold, Rolf
, p. 447 - 451 (1995)
(+)-Multifidene ((+)-1) has been synthesized starting from (R)-(cyclopent-2-enyl)methanol ((+)-2) via its chloroformate 4, Co-mediated radical cyclization reaction to the lactone (+)-6, and introduction of the olefine side chains.
A short chemoenzymatic synthesis of (+)-Multifidene and (+)-Viridiene
Lebreton, Jacques,Alphand, Veronique,Furstoss, Roland
, p. 1011 - 1014 (2007/10/03)
(+)-Multifidene 1 and (+)-Viridiene 2, the major constituents of some brown algae pheromones, were synthesized in five steps from racemic bicycloheptenone 3 via a novel microbiological Baeyer-Villiger oxidation performed using the fungi Cunninghamella echinulata.
Syntheses of Enantiomerically Pure ent-Multifidene and Related Compounds
Kramp, Peter,Helmchen, Guenter,Holmes, Andrew B.
, p. 551 - 552 (2007/10/02)
Enantiomers of multifidene and related compounds were synthesized from (1R)-7-syn-carboxy-2-norbornanone via Norrish Type I cleavage.
Synthesis of Cis Vicinally Disubstituted Cyclopentanes by Fragmentation of Bicycloheptan-6-ols. Total Synthesis of (+/-)-Multifidene
Burks, John E.,Crandall, Jack K.
, p. 4663 - 4670 (2007/10/02)
A fragmentation-olefination process has been developed for the conversion of bicycloheptan-6-ols bearing anion stabilizing functions at C-7 into cyclopentanes with vicinal and functionalized methyl substituents.Under appropriate conditions reasonab
