1755-01-7Relevant academic research and scientific papers
(η6-Arene) ruthenium(ii) complexes and metallo-papain hybrid as Lewis acid catalysts of Diels-Alder reaction in water
Talbi, Barisa,Haquette, Pierre,Martel, Annie,De Montigny, Frederic,Fosse, Celine,Cordier, Stephane,Roisnel, Thierry,Jaouen, Gerard,Salmain, Michele
, p. 5605 - 5607 (2010)
Covalent embedding of a (η6-arene) ruthenium(ii) complex into the protein papain gives rise to a metalloenzyme displaying a catalytic efficiency for a Lewis acid-mediated catalysed Diels-Alder reaction enhanced by two orders of magnitude in water.
Diels-Alder reactions in room-temperature ionic liquids
Fischer,Sethi,Welton,Woolf
, p. 793 - 796 (1999)
The Diels-Alder cycloaddition reaction between methyl acrylate and cyclopentadiene has been investigated in a number of air and moisture stable ionic liquids. The endo/exo ratio of the reaction has been used as an initial probe of the nature of the solvents.
Combining in situ FTIR spectroscopy, BTEM analysis, bulk density measurements and DFT for two Diels-Alder reactions. A general approach for partial molar volume and reaction volume analyses
Tjahjono, A. Martin,Feng, Gao,Hermanto, Martin Wijaya,Cechao, Foo,Garland, Marc
, p. 22194 - 22204 (2014)
Two organic reactions, namely the reaction of cyclopentadiene (CPD) and dimethyl acetylene dicarboxylate (DMAD) and the dimerization reaction of CPD were conducted in toluene at 298.1 K at atmospheric pressure and measured by in situ FTIR spectroscopy. Band-target entropy minimization (BTEM) analyses were employed for obtaining the pure component spectra of the solutes and their corresponding concentrations. The solute concentrations and the bulk density data were used to evaluate the partial molar volumes of the solute constituents. The partial molar volumes evaluated from this multi-component approach were in good agreement with those determined from independent binary solution measurements. The corresponding volumes of reaction for the CPD + DMAD and dimerization CPD + CPD reactions were determined to be -37 ± 3 cm 3 mol-1 and -31 ± 2 cm3 mol -1, respectively. For completeness, DFT calculations were performed and used to rationalize the vibration modes corresponding to the BTEM spectral estimates as well as to provide predictions of the molar volumes of the solutes. The present study demonstrates the usefulness of a combined spectroscopic, signal processing, bulk density measurement and DFT approach to the determination of partial molar volumes and volumes of reaction directly from the multi-component reactive systems. This journal is the Partner Organisations 2014.
Regioselective thermal cage-opening reactions of 4-amino substituted 1,3-bishomocubanones
Bakkeren, Frank J.A.D.,Schroeer, Frank,Klunder, Antonius J.H.,Zwanenburg, Binne
, p. 9531 - 9534 (1998)
Thermolysis of 4-substituted 1,3-bishomocubanones is strongly dependent on the electronic nature of the bridgehead substituent. 4-(N-benzyl)amido- substituted cage compounds 12 unexpectedly furnish bicyclic annelated cyclopentenones 13, whereas the 4-acet
Rhodium catalyzed one-step hydroamidation of cyclopentadiene and dicyclopentadiene
Behr, Arno,Levikov, Denys,Nürenberg, Edward
, p. 2783 - 2787 (2015)
A one-step rhodium catalyzed direct route from alkene to amide is presented via the hydroamidation reaction of cyclopentadiene and dicyclopentadiene with pyrrolidine. A homogeneous catalyst of [Rh(cod)Cl]2 without additional phosphorus ligands was established giving a 90% yield of the respective monoamide species of Dcpd with a high TOF of 1060 h-1. An important side reaction in hydroamidation reactions is the formation of oligomers of dicyclopentadiene. This unwanted reaction could be overcome by the optimum adjustment of the olefin/amine ratio. The desired atom economic hydroamidation, which uses the inexpensive bulk chemicals carbon monoxide and dicyclopentadiene, could be scaled up to a multigram scale with comparable catalyst activity.
Application of hierarchical pore molecular sieve in preparation process of cyclopentadiene and JP-10 aviation fuel
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Paragraph 0023; 0121-0126, (2021/07/01)
The invention relates to an application of a hierarchical pore molecular sieve in a the preparation process of cyclopentadiene and JP-10 aviation fuel. The hierarchical pore molecular sieve is one or two or more of an H-ZSM-5 molecular sieve, an H-beta molecular sieve, an H-Y molecular sieve, an H-USY molecular sieve, a La-Y molecular sieve and an H-MOR molecular sieve with a hierarchical pore structure, a sulfonated SBA-15 molecular sieve, a sulfonated MCM-41 molecular sieve, a sulfonated Ti-SBA-15 molecular sieve, a sulfonated MCM-41 molecular sieve, a sulfonated Zr-MCM-41 molecular sieve and a sulfonated Zr-SBA-15 molecular sieve; and the hierarchical pore structure comprises micropores and mesopores. The catalyst and the raw materials used in the method are cheap and easy to obtain, the preparation process is simple, and the hierarchical pore molecular sieve has high activity and selectivity for rearrangement reaction of furfuryl alcohol, hydrogenation reaction of hydroxyl cyclopentenone and dehydration reaction. The invention provides a cheap and efficient synthesis method for synthesizing the JP-10 aviation fuel from a lignocellulose-based platform compound furfuryl alcohol.
Cyclopentadiene fuels
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Page/Page column 7, (2021/08/04)
A method for making cyclopentadiene fuels comprising producing cyclopent-2-en-1-one or a mixture of cyclopent-2-en-1-one from a bio-based source. The cyclopent-2-en-1-one or the mixture of cyclopent-2-en-1-one is hydrogenated, thereby forming cyclopent-2-en-1-ol or a mixture of cyclopent-2-en-1-ol. The cyclopent-2-en-1-ol or the mixture of cyclopent-2-en-1-ol is dehydrated with a dehydrating agent, thereby forming cyclopentadiene or a mixture of cyclopentadiene. The cyclopentadiene or mixture of cyclopentadiene is converted to dicyclopentadiene or dihydrodicyclopentadiene. The dicyclopentadiene or dihydrodicyclopentadiene is hydrogenated, thereby forming tetrahydrodicyclopentadiene. The tetrahydrodicyclopentadiene is isomerized, thereby forming exo-tetrahydrodicyclopentadiene.
Method for Production of 5-Vinyl-2-Norbornene Using Porous Titanosilicate Catalyst
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Paragraph 0036-0040; 0045-0046, (2020/09/10)
The present invention relates to a method for manufacturing 5-vinyl-2-norbornene (VNB) by conducting reaction of cyclopentadiene (CPD) with 1,3-butadiene (BD). The method uses a porous titanosilicate catalyst, thereby providing an effect of increasing the selectivity of VNB and reducing the selectivity of by-product oligomer.(AA) CPD conversion ratio (%)(BB) VNB selectivity (%)(CC) THI selectivity (%)(DD) DCPD selectivity (%)(EE) Oligomer selectivity (%)(FF) Conversion ratio and selectivity (%)COPYRIGHT KIPO 2020
Making JP-10 Superfuel Affordable with a Lignocellulosic Platform Compound
Li, Guangyi,Hou, Baolin,Wang, Aiqin,Xin, Xuliang,Cong, Yu,Wang, Xiaodong,Li, Ning,Zhang, Tao
, p. 12154 - 12158 (2019/08/12)
The synthesis of renewable jet fuel from lignocellulosic platform compounds has drawn a lot of attention in recent years. So far, most work has concentrated on the production of conventional jet fuels. JP-10 is an advanced jet fuel currently obtained from fossil energy. Due to its excellent properties, JP-10 has been widely used in military aircraft. However, the high price and low availability limit its application in civil aviation. Here, we report a new strategy for the synthesis of bio-JP-10 fuel from furfuryl alcohol that is produced on an industrial scale from agricultural and forestry residues. Under the optimized conditions, bio-JP-10 fuel was produced with high overall carbon yields (≈65 %). A preliminary economic analysis indicates that the price of bio-JP-10 fuel can be greatly decreased from ≈7091 US$/ton (by fossil route) to less than 5600 US$/ton using our new strategy. This work makes the practical application of bio-JP-10 fuel forseeable.
Method for preparing JP-10 aviation fuel from furfuryl alcohol
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Paragraph 0129; 0130; 0132, (2018/06/16)
The invention relates to a method for preparing JP-10 aviation fuel from furfuryl alcohol. The method for preparing JP-10 aviation fuel by taking the furfuryl alcohol as a raw material is totally divided into six reactions as follows: a first reaction of carrying out a rearrangement reaction on a furfuryl alcohol solution in the presence of a base catalyst or under the condition that any catalystis not added to prepare hydroxy cyclopentenone; a second reaction of reacting the hydroxy cyclopentenone and hydrogen under catalysis of a hydrogenation catalyst so as to prepare 1,3-cyclopendiol; a third reaction of dehydrating the 1,3-cyclopendiol to prepare cyclopentadiene; a fourth reaction of carrying out a D-A reaction on the cyclopentadiene to produce dicyclopentadiene; a fifth reaction ofhydrogenating the dicyclopentadiene to produce endo-tetrahydrodicyclotadiene; and a sixth reaction of performing isomerization on the endo-tetrahydrodicyclotadiene to produce hanging type tetrahydrodicyclopentadiene, wherein the prepared hanging type tetrahydrodicyclopentadiene can directly serve as the JP-10 aviation fuel. The invention provides a cheap high-efficiency synthetic method for synthesizing the JP-10 aviation fuel from a lignocelluloses-based platform chemical compound, namely furfuryl alcohol.
