52890-23-0

Upstream product

• 52890-22-9 ethyl 3-(2-methylidenecyclohexyl)propionate 
• 1125-99-1 1-(1-Cyclohexen-1-yl)pyrrolidine 
• 4095-02-7 3-(2-oxocyclohexyl)propionic acid ethyl ester 

Downstream Products

• 52890-25-2 3-(2'-Methylencyclohexyl)propylbromid 
• 153446-20-9 3-(2-methylenecyclohexyl)propyl azide 
• 107175-53-1 Methanesulfonic acid 3-(2-methylene-cyclohexyl)-propyl ester 
• 52890-20-7 4-Nitro-benzenesulfonic acid 3-(2-methylene-cyclohexyl)-propyl ester 

Relevant academic research and scientific papers

Epoxide-initiated electrophilic cyclization of azides: A novel route for the stereoselective construction of azabicyclic ring systems and total synthesis of (±)-indolizidine 167B and 209D

(Matrix presented) A novel and general method for the stereoselective construction of 5-hydroxymethyl azabicyclic ring skeletons based on epoxide initiated electrophilic cyclization of azides has been developed and applied in the synthesis of (±)-indolizi

Epoxide-Initiated Cationic Cyclization of Azides: A Novel Method for the Stereoselective Construction of 5-Hydroxymethyl Azabicyclic Compounds and Application in the Stereo- and Enantioselective Total Synthesis of (+)- and (-)-Indolizidine 167B and 209D

A novel and general method has been developed for the stereoselective construction of 5-hydroxymethyl azabicyclic ring skeletons based on epoxide-initiated cationic cyclization of azides. The key cyclization reaction was systematically studied with the mo