52901-70-9

Basic information

• Product Name: Mo(CO)5(η1-1,2-bis(diphenylphosphino)ethane)
• CAS NO: 52901-70-9
• Molecular Weight: 634.416
• Mol File: 52901-70-9.mol

Chemical Properties

• CAS DataBase Reference: Mo(CO)5(η1-1,2-bis(diphenylphosphino)ethane)(CAS DataBase Reference)
• NIST Chemistry Reference: Mo(CO)5(η1-1,2-bis(diphenylphosphino)ethane)(52901-70-9)
• EPA Substance Registry System: Mo(CO)5(η1-1,2-bis(diphenylphosphino)ethane)(52901-70-9)

Safety Data

• Hazardous Substances Data: 52901-70-9(Hazardous Substances Data)

Upstream product

• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 
• 13939-06-5 molybdenum hexacarbonyl 

Downstream Products

• 152223-53-5 (CO)5Mo(μ-1,3-bis(diphenylphosphino)propane)W(CO)5 
• 75365-60-5 (CO)5Mo(μ-1,2-bis(diphenylphosphino)ethane)W(CO)5 
• 151932-70-6 trans-Cr(CO)4((1,2-bis(diphenylphosphino)ethane)Mo(CO)5)2 
• 75365-61-6 (CO)5Mo(μ-1,2-bis(diphenylphosphino)ethane)Cr(CO)5 

Relevant articles and documents

Substituted metal carbonyls. XXIII. Syntheses of unicoordinated diphosphine complexes of Cr and Mo and their entry into heterobimetallics MM'(CO)10(μ-P-P) as metalloligands

A series of pentacarbonyl complexes of chromium and molybdenum with unicoordinated-diphosphines, M(CO)5(η1-P-P) (P-P=dppe, dppp, dppb) has been prepared by amine oxide-induced phosphine substitution of the binary carbonyls.The basicity of the pendant phosphine groups was demonstrated by their ready conversion to the diphosphine-bridged heterobimetallic complexes (OC)5M(μ-P-P)M'(CO)5 (M,M'=Cr, Mo, W; M M') in the presence of M'(CO)5(CH3CN).The complexes were characterized by IR and NMR (1H and 31P-) spectroscopy.