52909-80-5

Upstream product

• 111-26-2 hexan-1-amine 
• 126-81-8 dimedone 
• 3471-13-4 dimedone 

Downstream Products

• 145801-83-8 N-(5,5-dimethyl-3-oxocyclohex-1-enyl)-N-hexylpent-4-enamide 
• 152496-56-5 2-allyloxy,N-(5,5-dimethyl-3-oxo-cyclohex-1-enyl),N-hexyl-acetamide 
• 175469-19-9 N-(5,5-dimethyl-3-oxo-cyclohex-1-enyl) N-hexyl 2-diallylaminoacetamide 
• 183674-33-1 N-(5,5-dimethyl-3-oxocyclohex-1-enyl)-N-hexyl-2-(cyclopent-2-enyl)acetamide 
• 102688-98-2 2-Bromo-3-hexylamino-5,5-dimethyl-cyclohex-2-enone 

Relevant academic research and scientific papers

Photorearrangement of N-alkanoyl β-enaminones. Application to the synthesis of α-amino-β,γ-unsaturated acid derivatives

The irradiation of N-alkanoyll-β-enaminones lead to the formation of spiranic β-lactams which undergo C-N bond cleavage during chromatography on alumina giving cycloalkenones functionalized at position 3. This new rearrangement has been applied to the synthesis of α-amino-β,γ-unsaturated amides in one step and gives convenient yields.

Intramolecular [2 + 2] photocvcloaddition of N-alkenovl-β-enaminones

The photolysis of cyclic N-alkenoyl β-enaminones is described. In general, a very regio- and stereoselective intramolecular [2 + 2] photocydoaddition was observed. The limitations of the reaction process are discussed. The main competitive reaction, which