52920-19-1

Basic information

• Product Name: 2-(4-methylbenzoyl)-benzaldehyde
• Synonyms: 2-(4-methylbenzoyl)-benzaldehyde
• CAS NO: 52920-19-1
• Molecular Weight: 224.259
• Mol File: 52920-19-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(4-methylbenzoyl)-benzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-methylbenzoyl)-benzaldehyde(52920-19-1)
• EPA Substance Registry System: 2-(4-methylbenzoyl)-benzaldehyde(52920-19-1)

Safety Data

• Hazardous Substances Data: 52920-19-1(Hazardous Substances Data)

Upstream product

• 125741-53-9 4-methylbenzoic acid (2-hydroxybenzylidene)-hydrazide 
• 122334-36-5 N-methoxy-N,4-dimethylbenzamide 
• 35822-58-3 2-bromobenzaldehyde diethyl acetal 

Downstream Products

• 21615-75-8 3-(4-tolyl)-isobenzofuranone 

Relevant articles and documents

Cobalt-catalyzed enantioselective intramolecular hydroacylation of ketones and olefins

Cobalt-chiral diphoshine catalytic systems promote intramolecular hydroacylation reactions of 2-acylbenzaldehydes and 2-alkenylbenzaldehydes to afford phthalide and indanone derivatives, respectively, in moderate to good yields with high enantioselectivities. The ketone hydroacylation did not exhibit a significant H/D kinetic isotope effect (KIE) with respect to the aldehyde C-H bond, indicating that C-H activation would not be involved in the rate-limiting step.

Polystyrene-supported iodobenzene diacetate (PSIBD)-mediated synthesis of 1,2-diacylbenzenes from 2-hydroxyaryl aldehyde/ketone acylhydrazones

Synthesis of some new 1,2-diacylbenzenes is described by the oxidation of 2-hydroxyaryl aldehyde/ketone acylhydrazones using polystyrene-supported iodobenzene diacetate (PSIBD) in good yield. Copyright Taylor & Francis Group, LLC.