52922-83-5Relevant academic research and scientific papers
Oxidation of substituted phenols with chlorine dioxide
Loginov,Chukicheva,Kuchin
experimental part, p. 1501 - 1503 (2012/03/10)
Chlorine dioxide was used to oxidize sterically hindered phenols and their derivatives (2,6-di-tert-butylphenol, 2,6-diisobornylphenol, 2,6-di-tert-butyl-4-methylphenol, 2,6-diisobornyl-4-methylphenol, and 3,5-diisobornyl-4-hydroxybenzaldehyde) in organic solvent. Pleiades Publishing, Ltd., 2011.
OXYGENATION OF 2,6-DI-t-BUTYLPHENOLS WITH SUPEROXO Co(lll) COMPLEXES
Nishinaga, A.,Tomita, H.,Matsuura, T.
, p. 2833 - 2836 (2007/10/02)
Superoxo Co(lll) complexes, *3 where X= Et3N(+) and (Ph3P)2N(+), mediate the dioxygen incorporation into 2,6-di-t-butylphenols (1) with the same regioselectivity as that in the base-catalyzed oxygenation of 1.The superoxo species acts as a base but is not incorporated into the substrate.
