52954-45-7

Basic information

• Product Name: 2-Octanol, 1-(phenylseleno)-
• CAS NO: 52954-45-7
• Molecular Formula: C14H22OSe
• Molecular Weight: 285.288
• Mol File: 52954-45-7.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: 2-Octanol, 1-(phenylseleno)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Octanol, 1-(phenylseleno)-(52954-45-7)
• EPA Substance Registry System: 2-Octanol, 1-(phenylseleno)-(52954-45-7)

Safety Data

• Hazardous Substances Data: 52954-45-7(Hazardous Substances Data)

Upstream product

• 29680-62-4 Tris(phenylseleno)borane 
• 2984-50-1 1,2-Epoxyoctane 
• 1666-13-3 diphenyl diselenide 
• 22859-62-7 lithio-phenylselenyl-methane 
• 59554-52-8 C₂H₅LiSe 
• 111-71-7 heptanal 
• 111-66-0 oct-1-ene 
• 1427290-04-7 1-(phenylseleno)-1,1-(S_S,S_S)-bis(p-tolylsulfinyl)methane 
• 34837-55-3 Phenylselenyl bromide 
• 67545-97-5 n-octyl phenyl selenoxide 
• 71766-38-6 Dodecyl phenyl selenoxide 
• 65275-53-8 β-Phenethyl-phenyl-selenoxid 
• 65275-52-7 Isobutyl(phenyl)selenoxid 
• 65275-51-6 n-propyl phenyl selenoxide 

Downstream Products

• 2984-50-1 1,2-Epoxyoctane 
• 67007-28-7 (RS)-O-acetyl-1-(phenylseleno)-2-octanol 
• 146896-33-5 methyl 5-<(phenylseleno)methyl>-4-oxa-2-undecenoate 

Relevant articles and documents

Iodosobenzene-Mediated Three-Component Selenofunctionalization of Olefins

A three-component reaction of olefin, diselenide and water, alcohols, phenol, carboxylic acid, or amine by a commercially available hypervalent iodine(III) reagent, PhIO, was developed. This method provides access to a wide range of vicinally functionalized selenoderivatives under ambient conditions with mostly excellent yields and high diastereoselectivity. The developed reaction displays high levels of functional group compatibility and is suitable for the late-stage functionalization of styrene-functionalized biomolecules. Preliminary investigations on the mechanism of the reaction are also presented.

Ultrasound assisted ring-opening reaction of epoxides with 1,2-diphenyldiselenide

Ultrasound assisted ring-opening of epoxides with 1,2-diphenyldiselenide in PEG-400/H2O in the presence of sodium dithionite has been developed, affording β-hydroxy selenides with high regioselectivity in good to excellent yields. Importantly,

Active metallic indium-mediated ring-opening of epoxides with diphenyl diselenides: A novel one-pot synthesis of β-hydroxy selenides in aqueous media

An efficient and simple one-pot procedure for the synthesis of β-hydroxy selenides in aqueous media through highly regioselective ring-opening of epoxides with diphenyl diselenide in the presence of active metallic indium is described.