52954-46-8

Basic information

• Product Name: 1-Octanol, 2-(phenylseleno)-
• CAS NO: 52954-46-8
• Molecular Formula: C14H22OSe
• Molecular Weight: 285.288
• Mol File: 52954-46-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-Octanol, 2-(phenylseleno)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Octanol, 2-(phenylseleno)-(52954-46-8)
• EPA Substance Registry System: 1-Octanol, 2-(phenylseleno)-(52954-46-8)

Safety Data

• Hazardous Substances Data: 52954-46-8(Hazardous Substances Data)

Upstream product

• 29680-62-4 Tris(phenylseleno)borane 
• 2984-50-1 1,2-Epoxyoctane 
• 111-66-0 oct-1-ene 
• 1666-13-3 diphenyl diselenide 

Relevant articles and documents

Iodosobenzene-Mediated Three-Component Selenofunctionalization of Olefins

A three-component reaction of olefin, diselenide and water, alcohols, phenol, carboxylic acid, or amine by a commercially available hypervalent iodine(III) reagent, PhIO, was developed. This method provides access to a wide range of vicinally functionalized selenoderivatives under ambient conditions with mostly excellent yields and high diastereoselectivity. The developed reaction displays high levels of functional group compatibility and is suitable for the late-stage functionalization of styrene-functionalized biomolecules. Preliminary investigations on the mechanism of the reaction are also presented.

UNUSUAL REACTIVITY OF SELENOBORANES TOWARDS EPOXIDES: NEW SELECTIVE ROUTES TO β-HYDROXYSELENIDES AND ALLYLALCOHOLS

Selenoboranes react with terminal, α, β- di- and trisubstituted epoxides to produce β-hydroxyselenides (or olefins) in the two first cases and allyl alcohols in the last one.A very high stereodescrimination has been observed for α,β-disubstituted epoxides: the cis epoxide being much more reactive.