53153-81-4Relevant academic research and scientific papers
P(RNCH2CH2)3N-Catalyzed synthesis of β-hydroxy nitriles
Kisanga, Philip,McLeod, Dale,D'Sa, Bosco,Verkade, John
, p. 3090 - 3094 (1999)
We herein report the successful synthesis of β-hydroxy nitriles in very good to excellent yields from aldehydes and ketones in a simple reaction that is promoted by strong nonionic bases of the title type. The reaction occurs in the presence of magnesium salts which activate the carbonyl group and stabilizes the enolate thus produced.
ALIPHATIC NITRILE WITH ROSY ODOR
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Page/Page column 11; 12, (2016/11/07)
The present invention concerns compound of formula (I) in the form of any one of its stereoisomers or a mixture thereof, and wherein R1 and R1', independently from each other, represent a hydrogen atom or a methyl group provided that one of said groups represent a hydrogen atom and the other a methyl group; R2 and R3, independently from each other, represent substituents of the saturated ring and are a hydrogen atom or a C1-3 alkyl group; and n is an integer varying between 1 and 4; and their use in perfumery to impart odor notes of the floral, rosy type.
