53170-70-0

Upstream product

• 16714-25-3 2-azidobenzaldehyde 
• 603-35-0 triphenylphosphine 
• 16714-26-4 1-(2-azido-phenyl)-ethanone 

Downstream Products

• 17437-51-3 N-(ethoxycarbonyl)triphenylphosphinimine 
• 64704-62-7 N-(2-(4-methylquinolin-2-yl)phenyl)benzamide 
• 154089-01-7 4-Methyl-N-[2-(4-methyl-quinolin-2-yl)-phenyl]-benzamide 
• 154088-94-5 1,3-Bis-(4-fluoro-phenyl)-1-(4-methylene-4H-benzo[d][1,3]oxazin-2-yl)-urea 
• 154089-02-8 2-<2-(4-methoxybenzoylamino)phenyl>-4-methylquinoline 
• 154088-93-4 1,3-Bis-(4-methoxy-phenyl)-1-(4-methylene-4H-benzo[d][1,3]oxazin-2-yl)-urea 
• 17436-52-1 benzoyliminotriphenylphosphorane 
• 6637-33-8 2-(2'-aminophenyl)-4-methylquinoline 

Relevant academic research and scientific papers

Access to 1: H -indazoles, 1 H -benzoindazoles and 1 H -azaindazoles from (het)aryl azides: A one-pot Staudinger-aza-Wittig reaction leading to N-N bond formation?

The synthesis of various substituted 1H-indazoles is reported through N-N bond formation from an iminophosphorane derivative. Supported by control experiments, an original Staudinger-aza-Wittig tandem mechanism is proposed for this transformation.

Preparation and Synthetic Applications of Iminophosphoranes Derived from o-Substituted Arylazides: Preparation of PyrazoloIndazole, 4H-3,1-Benzoxazine and Quinoline Derivatives. Crystal structure of 2--4-methylquino

The Staudinger reaction of several ortho-substituted arylazides with triphenylphosphine has been studied.The reaction product is found to be strongly dependent on the nature of the ortho-substituent.The Aza Wittig-type reaction of iminophosphorane derived