53171-63-4

Basic information

• Product Name: (+/-)-3-oximino-1,4,4-trimethylbicyclo<3.2.0>heptane
• CAS NO: 53171-63-4
• Molecular Weight: 167.251
• Mol File: 53171-63-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+/-)-3-oximino-1,4,4-trimethylbicyclo<3.2.0>heptane(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-3-oximino-1,4,4-trimethylbicyclo<3.2.0>heptane(53171-63-4)
• EPA Substance Registry System: (+/-)-3-oximino-1,4,4-trimethylbicyclo<3.2.0>heptane(53171-63-4)

Safety Data

• Hazardous Substances Data: 53171-63-4(Hazardous Substances Data)

Upstream product

• 503-93-5 eucarvone 
• 870-63-3 prenyl bromide 
• 111455-70-0 Acetic acid 2,2-dimethyl-1-(2-methyl-allyl)-but-3-enyl ester 
• 111455-68-6 (+/-)3,3-dimethylhept-1-en-4-ol-6-one 
• 92121-72-7 (1S,5S)-1,4,4-Trimethyl-bicyclo[3.2.0]heptan-3-ol 
• 127808-17-7 2,5,5,-trimethylhept-1,6-dien-4-ol 
• 5820-05-3 2,2-dimethylbut-3-enal 
• 63305-89-5 α-(1,1-dimethyl-2-propenyl)-2-methyl-1,3-dioxolane-2-ethanol 
• 53171-64-5 (+/-)1,4,4-trimethylbicyclo<3.2.0>heptan-3-one 
• 53171-52-1 1,4,4-trimethyl-cis-bicyclo<3.2.0>heptan-2-one 

Downstream Products

• 29578-30-1 cis-1-methyl-2-(1-methylethenyl)-cyclobutaneacetic acid 
• 26532-22-9 (1R, 2S)-grandisol 
• 68225-44-5 2-[(1S,2R)-1-methyl-2-(prop-1-en-2-yl)cyclobutyl]acetic acid 
• 55760-14-0 1-Cyanomethyl-2-isopropyliden-1-methylcyclobutan 
• 26532-22-9 grandisol 

Relevant articles and documents

STEREOSELECTIVE TOTAL SYNTHESIS OF RACEMIC GRANDISOL via 3-OXIMINO-1,4,4-TRIMETHYLBICYCLOHEPTANE. AN IMPROVED PRACTICAL PROCEDURE.

(+/-)Grandisol was stereoselectively obtained via 1,4,4-trimethylbicycloheptane-3-one and its oxime by an improved procedure. 2,5,5-trimethylhept-1,6-dien-4-ol, the open chain molecule, was synthesized by two routes.Its conversion into (+/-)grandisol was performed emploing the photobicyclization as key step.